Abstract:
The currently known methods for the preparation of vinyl ethers, vinyl sulfides and enamines are analyzed and described systematically. The published data on the reactions of alcohols, thiols and various nitrogen-containing compounds with acetylene, resulting in the corresponding vinyl derivatives, are considered. The attention is focused on the application of convenient acetylene sources. Other modern approaches to the synthesis of vinyl derivatives are described in detail, including vinyl exchange and metathesis reactions, various types of cross-coupling and cleavage of organic compounds. Some specific synthetic routes to vinyl ethers, vinyl sulfides and enamines are presented in the last Section.
The bibliography includes 262 references.
Citation:
M. S. Ledovskaya, V. V. Voronin, K. S. Rodygin, “Methods for the synthesis of O-, S- and N-vinyl derivatives”, Russian Chem. Reviews, 87:2 (2018), 167–191
Chloe L. Johnson, Daniel J. Storm, M. Arif Sajjad, Matthew R. Gyton, Simon B. Duckett, Stuart A. Macgregor, Andrew S. Weller, Miquel Navarro, Jesús Campos, Angew Chem Int Ed, 63:30 (2024)
L. Anders Hammarback, Tania Medina-Gil, Anna Sadurní, Antonio M. Echavarren, Org. Lett., 2024
Chloe G. Williams, Sepand K. Nistanaki, Krista Dong, Woojin Lee, Kendall N. Houk, Hosea M. Nelson, Org. Lett., 26:23 (2024), 4847
Saša Opačak, Sergey Tin, Adv Synth Catal, 2024
Chloe L. Johnson, Daniel J. Storm, M. Arif Sajjad, Matthew R. Gyton, Simon B. Duckett, Stuart A. Macgregor, Andrew S. Weller, Miquel Navarro, Jesús Campos, Angewandte Chemie, 136:30 (2024)
M. S. Ledovskaya, V. V. Voronin, Russ J Gen Chem, 94:11 (2024), 2833
V. V. Voronin, M. S. Ledovskaya, Russ J Gen Chem, 94:12 (2024), 3155