|
This article is cited in 3 scientific papers (total in 3 papers)
Charge transfer and interface properties in inorganic superstructures and composites
I. S. Flyaginaa, A. A. Petrovb, V. S. Pervovb a Institute of Physical Chemistry and Electro Chemistry, Russian Academy of Sciences, Moscow
b Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
Abstract:
The processes of charge transfer and electronic reconstruction at interfaces of inorganic superstructures and composites have not yet been adequately investigated. This review integrates and analyzes the results of theoretical and experimental studies of structural and electronic effects at interfaces of metal oxide or chalcogenide superstructures and composites. Charge transfer and, hence, change in interface properties compared to the properties of substructures are shown to be determined by the preparation method of composites and chemical nature of the superstructures, incommensurability of structural parameters and valence states of the constituent metals. The changes are maximal for nanoheterostructures, and the degree of change is related to electronic conductivity of substructures. The macroscopic properties of the composite materials depend on the amount of interfaces in their bulk. The bibliography includes 66 references.
Received: 09.06.2015
Citation:
I. S. Flyagina, A. A. Petrov, V. S. Pervov, “Charge transfer and interface properties in inorganic superstructures and composites”, Usp. Khim., 85:6 (2016), 610–618; Russian Chem. Reviews, 85:6 (2016), 610–618
Linking options:
https://www.mathnet.ru/eng/rcr4112https://doi.org/10.1070/RCR4578 https://www.mathnet.ru/eng/rcr/v85/i6/p610
|
Statistics & downloads: |
Abstract page: | 110 |
|