Abstract:
Problems of the involvement of molecular complexes of oxygen with variable-valence metal compounds in the liquid-phase oxidation of organic compounds, including the chain initiation reactions in radical chain oxidation, via the interaction of such complexes with the hydrocarbon are considered. The possibility of the operation of mechanisms resembling those of enzymic oxidation is analysed. Despite the lack in many instances of unambiguous evidence for the occurrence of the oxidation reaction via a mono- or di-oxygenase mechanism, one can assume that the reaction conditions and mechanisms in many chemical systems are close to those in biological systems. The bibliography includes 119 references.
Bibliographic databases:
Document Type:
Article
UDC:
547.40-71; 547.93
Language: English
Original paper language: Russian
Citation:
I. P. Skibida, “Activation of Molecular Oxygen by Metal Complexes and Its Role in the Mechanism of Liquid Phase Oxidation”, Usp. Khim., 54:9 (1985), 1487–1504; Russian Chem. Reviews, 54:9 (1985), 875–884
Linking options:
https://www.mathnet.ru/eng/rcr3661
https://doi.org/10.1070/RC1985v054n09ABEH003118
https://www.mathnet.ru/eng/rcr/v54/i9/p1487
This publication is cited in the following 7 articles:
S. Sh. Latypova, E. A. Eseva, N. A. Sinikova, A. V. Akopyan, Pet. Chem., 63:11 (2023), 1274
S. N. Kholuiskaya, A. F. Efremkin, V. V. Minin, Russ. J. Inorg. Chem., 56:2 (2011), 252
G. Krishnamurthy, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 41:6 (2011), 590
Andreja Bakac, Progress in Inorganic Chemistry, 43, Progress in Inorganic Chemistry, 1995, 267
Walt Partenheimer, Journal of Molecular Catalysis, 67:1 (1991), 35
E A Karakhanov, S Yu Narin, A G Dedov, Applied Organom Chemis, 5:6 (1991), 445
László Markó, Journal of Organometallic Chemistry, 343:1-3 (1988), 399
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