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Russian Chemical Reviews, 1985, Volume 54, Issue 9, Pages 885–897
DOI: https://doi.org/10.1070/RC1985v054n09ABEH003119
(Mi rcr3662)
 

This article is cited in 2 scientific papers (total in 2 papers)

Diffusion and Sorption of Aqueous Electrolyte Solutions in Polymers

G. E. Zaikov

Institute of Chemical Physics of the USSR Academy of Sciences, Moscow
English full-text Citations (2)
Abstract: The diffusion and solubility of electrolytes in polymers of different types (hydrophobic, hydrophilic, and moderately swelling) are examined. Diffusional transport in such systems is characterised by a number of features: dissociation, ion hydration, the formation of water clusters, and interaction with the functional groups of the polymer. The concentration dependence of the diffusion coefficients is analysed taking into account these effects and also the influence of the volume fraction of the polymer on the diffusion parameters. The mechanism of the distribution of the electrolyte in the hydrophobic and hydrophilic matrices is examined; it is shown that in the latter case account must be taken of the electrostatic factor, which influences the solubility of ions in polymers with ionogenic groups.
The bibliography includes 60 references.
Russian version:
Uspekhi Khimii, 1985, Volume 54, Issue 9, Pages 1505–1526
DOI: https://doi.org/10.1070/RC1985v054n09ABEH003119
Bibliographic databases:
Document Type: Article
UDC: 547.913
Language: English
Original paper language: Russian


Citation: G. E. Zaikov, “Diffusion and Sorption of Aqueous Electrolyte Solutions in Polymers”, Usp. Khim., 54:9 (1985), 1505–1526; Russian Chem. Reviews, 54:9 (1985), 885–897
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  • This publication is cited in the following 2 articles:
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