Abstract:
Methods for the investigation of elementary chemical reactions and molecular motions on the basis of the EPR spectra of radical pairs are examined. The results of the study of the stereochemistry and kinetics of processes involving radical pairs are used to discuss the nature of the characteristic features of the elementary solid-phase reactions: the existence of a broad spectrum of the frequencies of the reactions and molecular motions, the reaction mechanisms at low temperatures, and the influence of intra- and inter-molecular motions on the rates of chemical reactions. The bibliography includes 92 references.
Bibliographic databases:
Document Type:
Article
UDC:
538.113+541
Language: English
Original paper language: Russian
Citation:
O. E. Yakimchenko, Ya. S. Lebedev, “Radical Pairs in the Study of Elementary Chemical Reactions in Solid Organic Substances”, Usp. Khim., 47:6 (1978), 1018–1047; Russian Chem. Reviews, 47:6 (1978), 531–548
Linking options:
https://www.mathnet.ru/eng/rcr3062
https://doi.org/10.1070/RC1978v047n06ABEH002237
https://www.mathnet.ru/eng/rcr/v47/i6/p1018
This publication is cited in the following 18 articles:
Ya. S. Lebedev, O. Ye. Yakimchenko, EPR Imaging and In Vivo EPR, 2018, 25
Dzuba S., Uspekhi Khimii, 74:7 (2005), 686–706
Vladimir A Tolkatchev, Chemical Physics, 289:2-3 (2003), 335
E. Ya. Davydov, A. P. Vorotnikov, V. P. Pustoshnyi, G. B. Pariiskii, Russian Chem. Reviews, 69:10 (2000), 899–909
A. M. Raitsimring, P. Basu, N. V. Shokhirev, J. H. Enemark, Appl. Magn. Reson., 9:2 (1995), 173
Eugenii Ya. Misochko, Viktor A. Benderskii, Albert U. Goldschleger, Alexander V. Akimov, Mendeleev Communications, 4:6 (1994), 203
G. G. Lazarev, Zeitschrift für Physikalische Chemie, 173:2 (1991), 141
S. Ya. Kuchmii, A. I. Kryukov, Theor Exp Chem, 24:5 (1989), 546
A. I. Kryukov, S. Ya. Kuchmii, A. V. Korzhak, Theor Exp Chem, 24:6 (1988), 649
E.V. Boldyreva, Reactivity of Solids, 3:3 (1987), 185
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