Abstract:
We have synthesized two novel complexes of copper(II) trichloro acetate, Cu2(CCl3COO)3(OH)(H2O)4·H2O and Cu(CCl3COO)2(MeCN), and determined their crystal structures and thermal stability. While the complex with acetonitrile has a discrete binuclear paddle-wheel structure, typical of copper carboxylates, the aqua-hydroxo complex belongs to a novel unique chain–molecular type of basic copper complexes.
Citation:
O. S. Pushikhina, K. R. Volkova, E. V. Karpova, V. A. Tafeenko, M. A. Zakharov, “Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes”, Mendeleev Commun., 32:2 (2022), 208–211
Linking options:
https://www.mathnet.ru/eng/mendc615
https://www.mathnet.ru/eng/mendc/v32/i2/p208
This publication is cited in the following 3 articles:
Vnira R Akhmetova, Nail S Akhmadiev, Aidar T Gubaidullin, Aida I Samigullina, Andrey B Glazyrin, Rais A Sadykov, Diana V Ishmetova, Yulia V Vakhitova, “Novel binuclear copper(II) complexes with sulfanylpyrazole ligands: synthesis, crystal structure, fungicidal, cytostatic, and cytotoxic activity”, Metallomics, 16:6 (2024)
O. S. Pushikhina, E. V. Karpova, D. A. Tsarev, V. A. Tafeenko, T. B. Shatalova, “Characterization of New Pentanuclear Copper(II) and REE(III) Carboxylate Complexes”, Russ. J. Inorg. Chem., 68:9 (2023), 1313
O. S. Pushikhina, E. V. Karpova, D. A. Tsarev, V. A. Tafeenko, T. B. Shatalova, “Izuchenie svoistv novykh pyatiyadernykh karboksilatnykh kompleksov medi(II) i RZE(III)”, Žurnal neorganičeskoj himii, 68:9 (2023), 1324
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