Abstract:
Ruthenium(ii) complexes with chelating N-heterocyclic carbene (NHC) ligands were studied in the arylation of phenyl group in 2-phenylpyridine and 1-phenylpyrazole with aryl chlorides in water. Complexes with NHC-ligands containing a hemilabile coordinating N-carboxylatomethyl group enable fast and selective ortho-CH-diarylation in the absence of carboxylate-assisting additives.
Citation:
K. E. Shepelenko, K. A. Nikolaeva, M. A. Shevchenko, Yu. N. Tkachenko, M. E. Minyaev, V. M. Chernyshev, “Ruthenium complexes with chelating carboxylate-NHC ligands as efficient catalysts for C–H arylation in water”, Mendeleev Commun., 32:2 (2022), 205–207
Linking options:
https://www.mathnet.ru/eng/mendc614
https://www.mathnet.ru/eng/mendc/v32/i2/p205
This publication is cited in the following 11 articles:
I. G. Gnatiuk, K. A. Nikolaeva, K. E. Shepelenko, V. M. Chernyshev, “Structural effects of the carboxylate anion on Ru-catalyzed C—H arylation of (hetero)aromatic substrates containing N-donor directing group”, Russ Chem Bull, 73:3 (2024), 497
Öznur Doğan Ulu, Nevin Gürbüz, İsmail Özdemir, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2024
P. A. Petrov, S. A. Nikolaevskii, E. A. Filippova, N. B. Kompankov, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “New Polymorph of 1,3-Bis(2,6-di-isopropylphenyl)-4,5-Dichloroimidazole-2-Ylidene and a Cobalt Complex with this Compound”, J Struct Chem, 65:1 (2024), 117
Yu. N. Tkachenko, M. A. Shevchenko, I. V. Lavrentev, D. V. Pasyukov, M. E. Minyaev, V. M. Chernyshev, “Cyclization of 5,6-Diarylpyrrolo[3,4-d]pyrimidine-2,4-diones into Pyrrolo[1,2-f]phenanthridine Derivatives: Intramolecular C–H Arylation under Ru/NHC Catalysis”, Russ J Gen Chem, 94:2 (2024), 327
A. Yu. Chernenko, V. A. Baydikova, M. E. Minyaev, V. M. Chernyshev, “Nitron analogs containing an N-arylcarbamoylmethyl group and Pd complexes derived therefrom: synthesis and catalytic activity in the Suzuki—Miyaura reaction”, Russ Chem Bull, 73:4 (2024), 932
Mert Olgun Karataş, Ünzile Keleştemur, Ak{\i}n Mumcu, Nam{\i}k Özdemir, Ali Erdoğan, Hasan Küçükbay, “Silver and ruthenium complexes with anthracene functionalized N-heterocyclic carbene ligands: catalytic and cytotoxicity properties”, Transit Met Chem, 49:5 (2024), 365
A. Yu. Chernenko, K. E. Shepelenko, M. E. Minyaev, V. M. Chernyshev, “Novel ruthenium(ii) complexes with chelating 1,2,4-triazole NHC ligands and their catalytic activity in the transfer hydrogenation of ketones”, Mendeleev Commun., 34:3 (2024), 385–388
K. E. Shepelenko, I. G. Gnatiuk, M. E. Minyaev, V. M. Chernyshev, “Synthesis of furo[2,3-c]quinolinones via intramolecular C(3)–H arylation of furan core under Pd/NHC-catalysis”, Mendeleev Commun., 34:2 (2024), 198–200
S. A. Runikhina, A. A. Tsygankov, O. I. Afanasyev, D. A. Chusov, “Reductive α-alkylation of ketones with aldehydes at atmospheric pressure of carbon monoxide: the effect of fluoride activation in ruthenium catalysis”, Mendeleev Commun., 33:1 (2023), 17–20
A. Yu. Chernenko, V. A. Baydikova, A. V. Astakhov, M. E. Minyaev, V. M. Chernyshev, “Nickel-Catalyzed N-Arylation of C-Amino-1,2,4-triazoles with Arylboronic Acids”, Dokl Chem, 504:2 (2022), 93
K. E. Shepelenko, K. A. Nikolaeva, I. G. Gnatiuk, O. G. Garanzha, A. A. Alexandrov, M. E. Minyaev, V. M. Chernyshev, “Ruthenium(II)-catalyzed C(3)–H arylation of furan moiety in fuberidazole derivatives”, Mendeleev Commun., 32:4 (2022), 485–487
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