M. E. Buzoverov, T. Yu. Glazunova, E. Kh. Lermontova, “Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2”, Mendeleev Commun., 32:2 (2022), 212

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Mendeleev Communications, 2022, Volume 32, Issue 2, Pages 212–214
DOI: https://doi.org/10.1016/j.mencom.2022.03.019 (Mi mendc616)

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Synthesis, crystal structure and thermal properties of Na₂Ti(CF₃COO)₆(CF₃COOH)₂

M. E. Buzoverov, T. Yu. Glazunova, E. Kh. Lermontova

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (1072 kB) Citations (2)

DOI: https://doi.org/10.1016/j.mencom.2022.03.019

Graphic abstract: Synthesis, crystal structure and thermal properties of Na<sub>2</sub>Ti(CF<sub>3</sub>COO)<sub>6</sub>(CF<sub>3</sub>COOH)<sub>2</sub>

Abstract: The compound Na₂Ti(CF₃COO)₆(CF₃COOH)₂ was synthesized as colorless crystals, extremely unstable in air, by the reaction of TiCl₄ with trifluoroacetic acid and sodium trifluoroacetate. Crystallographic studies have shown that this sodium trifluoroacetatotitanate is the first example of a tetravalent titanium carboxylate [Ti(RCOO)₆]²– containing titanium in an octahedral environment of oxygen atoms of carboxylate groups. Thermal decomposition of Na₂Ti(CF₃COO)₆(CF₃COOH)₂ in an argon atmosphere results in the complex fluoride Na₂TiF₆.

Keywords: titanium, titanium coordination compounds, carboxylate complexes, trifluoroacetic acid, titanium trifluoroacetate.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.0 Mb)

Citation: M. E. Buzoverov, T. Yu. Glazunova, E. Kh. Lermontova, “Synthesis, crystal structure and thermal properties of Na₂Ti(CF₃COO)₆(CF₃COOH)₂”, Mendeleev Commun., 32:2 (2022), 212–214

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https://www.mathnet.ru/eng/mendc616

https://www.mathnet.ru/eng/mendc/v32/i2/p212

This publication is cited in the following 2 articles:

R. M. Zakalyukin, E. A. Levkevich, V. V. Grebenev, T. Yu. Glazunova, M. E. Buzoverov, A. S. Kumskov, “A New Way of Preparing Nanosized Tysonite Phases”, Bull. Russ. Acad. Sci. Phys., 87:10 (2023), 1417
R. M. Zakalyukin, E. A. Levkevich, V. V. Grebenev, T. Yu. Glazunova, M. E. Buzoverov, A. S. Kumskov, “A novel method for the preparation of nanosized tysonite phases”, Izvestiâ Akademii nauk SSSR. Seriâ fizičeskaâ, 87:10 (2023), 1381

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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