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Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 519–521
DOI: https://doi.org/10.1016/j.mencom.2023.06.025
(Mi mendc446)
 

This article is cited in 3 scientific papers (total in 3 papers)

Communications

Weak ferromagnetism in a diamagnetically diluted sublattice of $\mathrm{Fe^{3+}}$ ions in solid solutions $\mathrm{Y_{2-x}Fe_{1+x}TaO_7}$ ($x = 0\text{-}0.2$) with pyrochlore-like structure

A. V. Egoryshevaa, O. G. Ellerta, E. F. Popovaa, D. I. Kirdyankina, Yu. V. Maksimovb

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (732 kB) Citations (3)
Abstract: A series of layered solid solutions $\mathrm{Y_{2-x}Fe_{1+x}TaO_7}$ ($x = 0\text{-}0.2$) was synthesized and a structural transition (space group $R\overline{3}$ $\leftrightarrow$ space group $P3_{1}21$) was observed at $x=0.1$. In $\mathrm{Y_{2-x}Fe_{1+x}TaO_7}$, which belongs to both structural types, geometrically frustrated 2D sublattices of kagome-type are formed, in which $\mathrm{Fe^{3+}}$ ions are coupled by short-range antiferromagnetic interactions, and the transition to the spin glass state is observed at $T_g \sim 4.3 K$. A phenomenon of weak ferromagnetism has been detected, the cause of which is probably a small tilt of the $\mathrm{Fe^{3+}}$ spins due to the Dzyaloshinskii–Moriya antisymmetric superexchange.
Keywords: $\mathrm{Y_{2}FeTaO_7}$, solid solutions, structural transition, pyrochlore-like structure, spin glass, weak ferromagnetism, Dzyaloshinskii–Moriya interaction.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (927.1 Kb)
Citation: A. V. Egorysheva, O. G. Ellert, E. F. Popova, D. I. Kirdyankin, Yu. V. Maksimov, “Weak ferromagnetism in a diamagnetically diluted sublattice of $\mathrm{Fe^{3+}}$ ions in solid solutions $\mathrm{Y_{2-x}Fe_{1+x}TaO_7}$ ($x = 0\text{-}0.2$) with pyrochlore-like structure”, Mendeleev Commun., 33:4 (2023), 519–521
Citation in format AMSBIB
\Bibitem{EgoEllPop23}
\by A.~V.~Egorysheva, O.~G.~Ellert, E.~F.~Popova, D.~I.~Kirdyankin, Yu.~V.~Maksimov
\paper Weak ferromagnetism in a diamagnetically diluted sublattice of $\mathrm{Fe^{3+}}$ ions in solid solutions
$\mathrm{Y_{2-x}Fe_{1+x}TaO_7}$
($x = 0\text{-}0.2$)
with pyrochlore-like structure
\jour Mendeleev Commun.
\yr 2023
\vol 33
\issue 4
\pages 519--521
\mathnet{http://mi.mathnet.ru/mendc446}
\crossref{https://doi.org/10.1016/j.mencom.2023.06.025}
Linking options:
  • https://www.mathnet.ru/eng/mendc446
  • https://www.mathnet.ru/eng/mendc/v33/i4/p519
  • This publication is cited in the following 3 articles:
    1. Nadezhda A. Zhuk, Boris A. Makeev, Aleksandra V. Koroleva, Aleksey M. Lebedev, Olga V. Petrova, Sergey V. Nekipelov, Viktor N. Sivkov, “XPS and NEXAFS Characterization of Mg/Zn and Mn Codoped Bismuth Tantalate Pyrochlores”, Inorganics, 12:3 (2024), 74  crossref
    2. A. V. Egorysheva, E. F. Popova, O. G. Ellert, E. V. Khramov, S. Y. Kottsov, E. S. Kulikova, “Structural Features of Mg-Containing Solid Solutions Based on Y2FeTaO7”, Russ. J. Inorg. Chem., 2024  crossref
    3. O. G. Ellert, E. F. Popova, D. I. Kirdyankin, V. K. Imshennik, A. V. Egorysheva, “Canted antiferromagnetism in $\mathrm{Y_{2-x}Ca_xFeTaO_{7-\delta}}$ solid solutions with a pyrochlore-like structure”, Mendeleev Commun., 34:2 (2024), 291–293  mathnet  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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