Abstract:
Reversible transformations of a hybrid molecule based on [60]fullerene and a spiropyran moiety under conditions of combined photo- and electrochemical exposure were found. It has been established that the electrochemical oxidation of the UV-photoinduced colored form of the hybrid spiropyran in solution significantly accelerates the discoloration process and does not affect the fullerene part of the hybrid molecule. The research results are promising for designing a photo-electrochromic device that modulates electromagnetic radiation in the visible range of the spectrum.
Citation:
A. A. Nekrasov, N. V. Nekrasova, M. A. Savel'ev, A. A. Khuzin, V. A. Barachevsky, A. R. Tulyabaev, A. R. Tuktarov, “Electrochemical investigation of a photochromic spiropyran containing a pyrrolidinofullerene moiety”, Mendeleev Commun., 33:4 (2023), 505–508
Linking options:
https://www.mathnet.ru/eng/mendc442
https://www.mathnet.ru/eng/mendc/v33/i4/p505
This publication is cited in the following 2 articles:
O. L. Gribkova, I. R. Sayarov, V. A. Kabanova, A. A. Nekrasov, A. R. Tameev, “Electrodeposited Composite of Poly-3,4-ethylenedioxythiophene with Fullerenol Photoactive in the Near-IR Range”, Russ J Electrochem, 60:10 (2024), 813
Oxana Gribkova, Varvara Kabanova, Ildar Sayarov, Alexander Nekrasov, Alexey Tameev, “Near-Infrared Responsive Composites of Poly-3,4-Ethylenedioxythiophene with Fullerene Derivatives”, Polymers, 17:1 (2024), 14
Contact us: