Abstract:
A mild approach to the synthesis of the title cage aminophosphonate has been developed based on the intramolecular cyclization of 2-(2-benzylideneaminoethoxy)-1-phenylbenzo[e]-1,3,2-azaoxaphosphorin-4-one obtained from 1-phenyl-2-chlorobenzo[e]-1,3,2-azaoxaphosphorin-4-one and (2-benzylideneaminoethoxy)trimethylsilane. The structure of isolated diastereomers of the product was determined by NMR spectroscopy and single crystal X-ray diffraction analysis.
Citation:
M. N. Dimukhametov, G. A. Ivkova, I. A. Litvinov, R. R. Fayzullin, V. F. Mironov, “Synthesis and structure of stereoisomers of 3,4-benzo-5,10-diphenyl-1,3-diaza-7-oxa-6-phosphabicyclo[4.3.1]decane-2,6-dione”, Mendeleev Commun., 29:2 (2019), 150–152
Linking options:
https://www.mathnet.ru/eng/mendc1452
https://www.mathnet.ru/eng/mendc/v29/i2/p150
This publication is cited in the following 4 articles:
K. E. Metlushka, R. G. Zinnatullin, K. A. Nikitina, E. K. Badeeva, “Chiral 2-oxo-1,4,2-oxazaphosphorinanes: synthesis, structure and applications (a review)”, Žurnal obŝej himii, 93:9 (2023), 1365
K. E. Metlushka, R. G. Zinnatullin, K. A. Nikitina, E. K. Badeeva, “Chiral 2-Oxo-1,4,2-oxazaphosphorinanes: Synthesis, Structure, and Applications (A Review)”, Russ J Gen Chem, 93:9 (2023), 2237
M. N. Dimukhametov, V. F. Mironov, D. R. Islamov, I. A. Litvinov, O. I. Gnezdilov, Yu. V. Danilova, “Reaction of sodium N-benzylideneglycinate with dialkyl chlorophosphites in the presence of water”, Mendeleev Commun., 31:1 (2021), 107–109
O. I. Kolodiazhnyi, “Stereochemistry, mechanisms and applications of electrophilic reactions of organophosphorus compounds”, Russian Chem. Reviews, 89:5 (2020), 537–572
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