aDepartment of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary bSpectroscopic Research Division, Gedeon Richter Plc., Budapest, Hungary
Abstract:
The reaction of dimethyl (1-aryl-1-hydroxymethyl)phosphonates with 1-chloro-3-phospholene 1-oxides, diphenylphosphinic chloride or diphenyl chloridophosphonate affords the corresponding (1-phosphoryloxymethyl)phosphonates. The products with two different >P(O)– moieties exhibit characteristic δP shifts and 3JP,P couplings in the 31P NMR spectra.
Citation:
Z. Radai, V. Hodula, N. Z. Kiss, J. Koti, G. T. Keglevich, “Phosphorylation of (1-aryl-1-hydroxymethyl)phosphonates”, Mendeleev Commun., 29:2 (2019), 153–154
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https://www.mathnet.ru/eng/mendc1453
https://www.mathnet.ru/eng/mendc/v29/i2/p153
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