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Mendeleev Communications, 2020, Volume 30, Issue 5, Pages 592–595
DOI: https://doi.org/10.1016/j.mencom.2020.09.013
(Mi mendc1262)
 

This article is cited in 7 scientific papers (total in 7 papers)

Communications

Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands

I. N. Meshcheryakova, K. V. Arsenyeva, G. K. Fukin, V. K. Cherkasov, A. V. Piskunov

G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
Full-text PDF (414 kB) Citations (7)
Abstract: N-Heterocyclic carbene is a versatile ligand for the preparation of copper(i) and silver(i) derivatives bearing the radical anion forms of redox active o-benzoquinone and o-iminobenzoquinone. The paramagnetic three-coordinated copper(i) and silver(i) o-benzosemiquinone and o-iminobenzosemiquinone complexes were prepared and characterized by EPR spectroscopy and X-ray diffraction analysis.
Keywords: N-heterocyclic carbene, copper(i), silver(i), redox active ligand, o-benzosemiquinone, o-iminobenzosemiquinone, X-ray diffraction.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.0 Mb)


Citation: I. N. Meshcheryakova, K. V. Arsenyeva, G. K. Fukin, V. K. Cherkasov, A. V. Piskunov, “Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands”, Mendeleev Commun., 30:5 (2020), 592–595
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  • This publication is cited in the following 7 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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