Abstract:
N-Heterocyclic carbene is a versatile ligand for the preparation of copper(i) and silver(i) derivatives bearing the radical anion forms of redox active o-benzoquinone and o-iminobenzoquinone. The paramagnetic three-coordinated copper(i) and silver(i) o-benzosemiquinone and o-iminobenzosemiquinone complexes were prepared and characterized by EPR spectroscopy and X-ray diffraction analysis.
Citation:
I. N. Meshcheryakova, K. V. Arsenyeva, G. K. Fukin, V. K. Cherkasov, A. V. Piskunov, “Stable N-heterocyclic carbene derivatives of copper(i) and silver(i) containing radical anion redox active ligands”, Mendeleev Commun., 30:5 (2020), 592–595
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https://www.mathnet.ru/eng/mendc1262
https://www.mathnet.ru/eng/mendc/v30/i5/p592
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