aDepartment of Chemistry, University of Houston-Clear Lake, Houston, TX, USA bCollege of Chemistry and Materials Science, Northwest University, Xi’an, Shaanxi, P.R. China cCollege of Materials and Chemical Engineering, China Three Gorges University, Yichang, P.R. China.
Abstract:
Reaction of FeCl2·4H2O, 5-bromonicotinic acid and 4,4′-bipyridine under hydrothermal conditions produced a new isomer of [(Feiii)2Feii(μ3-O)(5-bromonicotinato)6]n, which represented 3D metal–organic covalent framework with trinuclear oxo-centered mixed valence iron clusters. Crystal structure of the isomer has been characterized by single crystal X-ray diffraction data and found distinct from the one for the known isomer with 2D structure.
Citation:
L. Fu, Q. Yang, D. Li, J. Y. Lu, “New 3D metal–organic framework isomer containing trinuclear oxo-centered mixed valence iron”, Mendeleev Commun., 30:5 (2020), 589–591
Linking options:
https://www.mathnet.ru/eng/mendc1261
https://www.mathnet.ru/eng/mendc/v30/i5/p589
This publication is cited in the following 3 articles:
Harrison S. Moore, Eleanor R. Kearns, Martin P. van Koeverden, Deanna M. D′Alessandro, Mixed‐Valence Systems, 2023, 393
G. I. Dzhardimalieva, V. A. Zhinzhilo, I. E. Uflyand, “Advances in the chemistry of composites of metal-organic frameworks”, Russian Chem. Reviews, 91:10 (2022), RCR5055
I. A. Lutsenko, M. A. Kiskin, D. E. Baravikov, Yu. V. Nelyubina, P. V. Primakov, I. L. Eremenko, “Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach”, Mendeleev Commun., 31:5 (2021), 628–630
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