E. A. Kuchuk, B. N. Mankaev, V. A. Serova, K. V. Zaitsev, A. V. Churakov, Yu. F. Oprunenko, G. S. Zaitseva, S. S. Karlov, “New dialkylenetriamine zinc complexes as highly efficient ROP catalysts”, Mendeleev Commun., 30:5 (2020), 596

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Mendeleev Communications, 2020, Volume 30, Issue 5, Pages 596–598
DOI: https://doi.org/10.1016/j.mencom.2020.09.014 (Mi mendc1263)

This article is cited in 8 scientific papers (total in 8 papers)

Communications

New dialkylenetriamine zinc complexes as highly efficient ROP catalysts

E. A. Kuchuk^a, B. N. Mankaev^a, V. A. Serova^a, K. V. Zaitsev^a, A. V. Churakov^b, Yu. F. Oprunenko^a, G. S. Zaitseva^a, S. S. Karlov^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (315 kB) Citations (8)

DOI: https://doi.org/10.1016/j.mencom.2020.09.014

Graphic abstract: New dialkylenetriamine zinc complexes as highly efficient ROP catalysts

Abstract: The reaction of Zn[N(SiMe₃)₂]₂ with N-alkyl-N-[ω- (pentafluorophenylamino)alkyl]-N-[2-(pentafluorophenylamino) ethyl]amines afforded new bicyclic zinc complexes. The complexes initiate ring-opening polymerization of ɛ-caprolactone and trimethylene carbonate to give the corresponding polymers with high molecular weight and satisfactory degree of polymerization.

Keywords: ring-opening polymerization, diamides, amines, zinc complex, biodegradable polymers, ɛ-caprolactone, trimethylene carbonate, 1,4,n-triazaalkanes, organofluorine compounds.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.2 Mb)

Citation: E. A. Kuchuk, B. N. Mankaev, V. A. Serova, K. V. Zaitsev, A. V. Churakov, Yu. F. Oprunenko, G. S. Zaitseva, S. S. Karlov, “New dialkylenetriamine zinc complexes as highly efficient ROP catalysts”, Mendeleev Commun., 30:5 (2020), 596–598

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https://www.mathnet.ru/eng/mendc/v30/i5/p596

This publication is cited in the following 8 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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