Аннотация:
Deactivated arenes (di- and tri-halobenzenes, acetophenone, benzophenone and methylbenzoate) have been shown to be alkylated by alkanes and cycloalkanes (propane, n-butane, cyclopentane) in the presence of superacid CBr4·2AlBr3 in the range –40 to 0 °C; in some cases selective and effective mono- or di-alkylation can be achieved.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. V. Orlinkov, I. S. Akhrem, L. V. Afanas'eva, E. I. Mysov, M. E. Vol'pin, “Alkylation of deactivated arenes by alkanes in the presence of aprotic organic superacid CBr4·2AlBr3”, Mendeleev Commun., 7:2 (1997), 61–63
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc4783
https://www.mathnet.ru/rus/mendc/v7/i2/p61
Эта публикация цитируется в следующих 9 статьяx:
Irena S. Akhrem, “Recent achievements in intermolecular sp3 C–H bond functionalization of organic compounds by superelectrophilic trihalomethyl metal complex”, Journal of Organometallic Chemistry, 793 (2015), 54
Irena Akhrem, Alexander Orlinkov, “Polyhalomethanes Combined with Lewis Acids in Alkane Chemistry”, Chem. Rev., 107:5 (2007), 2037
Catalysis by Metal Complexes, 21, Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, 2002, 21
Marina I. Shilina, Vladimir V. Smirnov, Olga R. Perlovskaya, Tatyana N. Rostovshchikova, “Theoretical and low-temperature IR spectroscopic studies of catalytic complexes of aluminum chloride with nitroalkanes and nitrobenzene”, Journal of Molecular Catalysis A: Chemical, 158:1 (2000), 495
M.I. Shilina, T.N. Rostovshchikova, O.V. Zagorskaya, V.V. Smirnov, “Application of low temperature IR spectroscopy for studies of catalyst properties and dynamics on the example of aluminum halide complexes”, Journal of Molecular Catalysis A: Chemical, 146:1-2 (1999), 335
Irena Akhrem, Alexander Orlinkov, Sergei Vitt, “Unprecedented facile reactions of propane and cycloalkanes with elemental sulfur leading to dialkylsulfides and dicycloalkylsulfides”, Inorganica Chimica Acta, 280:1-2 (1998), 355
I. S. Akhrem, A. V. Orlinkov, “Novel superelectrophilic complexes for low-temperature alkane and cycloalkane transformations”, Russ Chem Bull, 47:5 (1998), 740
I. S. Akhrem, I. M. Churilova, A. V. Orlinkov, L. V. Afanas'eva, S. V. Vitt, P. V. Petrovskii, “A new efficient and selective synthesis of ketones from alkanes or cycloalkanes, CO, and silanes in the presences of aprotic superacids”, Russ Chem Bull, 47:5 (1998), 918
A. V. ORLINKOV, I. S. AKHREM, L. V. AFANAS'EVA, E. I. MYSOV, M. E. VOL'PIN, “ChemInform Abstract: Alkylation of Deactivated Arenes by Alkanes in the Presence of Aprotic Organic Superacid CBr4×2AlBr3.”, ChemInform, 28:38 (1997)
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