Аннотация:
The consecutive alkylation of 9-isopropyl-6-phenyl-9H-purine with methyl 2-diazo-3,3,3-trifluoropropionate and diethyl diazomalonate proceeds at the phenyl substituent firstly viaortho-C–H activation under chelation-assistance of the purine core, followed by classical electrophilic metal carbenoid insertion to the C−H bond of a malonate moiety.
Образец цитирования:
M. M. Vinogradov, D. V. Vorobyeva, Yu. V. Nelyubina, S. N. Osipov, D. A. Loginov, “Unusual multiple insertion of diazo carbonyl compounds into (purin-6-yl)benzene derivative”, Mendeleev Commun., 30:4 (2020), 494–495
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc1234
https://www.mathnet.ru/rus/mendc/v30/i4/p494
Эта публикация цитируется в следующих 3 статьяx:
D. V. Vorobyeva, A. S. Bubnova, A. G. Buyanovskaya, S. N. Osipov, “Synthesis of CF3-substituted isoindolones via rhodium(iii)-catalyzed carbenoid C–H functionalization of aryl hydroxamates”, Mendeleev Commun., 33:1 (2023), 34–36
Sofya S. Kuvshinova, Yulia V. Nelyubina, Vladimir A. Larionov, Daria V. Vorobyeva, Sergey N. Osipov, Dmitry A. Loginov, “Half-sandwich complexes of group 9 metals with N,Nʹ-ligands for CF3-carbenoid alkylation of N-(pyrimidin-2-yl)indole”, Journal of Organometallic Chemistry, 946-947 (2021), 121899
Vladimir B. Kharitonov, Vladimir S. Ostrovskii, Yulia V. Nelyubina, Dmitry V. Muratov, Denis Chusov, Dmitry A. Loginov, “Tris(pyrazolyl)borate rhodium complexes. Application for reductive amination and esterification of aldehydes in the presence of carbon monoxide”, Journal of Organometallic Chemistry, 925 (2020), 121468
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