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Teoreticheskaya i Matematicheskaya Fizika, 1987, Volume 71, Number 3, Pages 426–440
(Mi tmf4972)
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This article is cited in 2 scientific papers (total in 2 papers)
Phase diagrams and singularity at the point of a phase transition of the first kind in lattice gas models
S. N. Isakov
Abstract:
Contour representation of the statistical sum of a $d$-dimensional $(d\geq 2)$ lattice gas
models with the pair finite potential is studied. On the complex plane of the chemical
potential $\mu$ the equation is found for the line of the phase transition of the first kind
between two phases with the arbitrarily complicated periodic ordering of atoms of the
lattice in the ground state in the assumption of the validity of Peierls' hypothesis. Inverse
temperature $\beta=T^{-1}$ is also considered as complex and having a sufficiently large
real part. Analyticity of the pressure outside the transition line is proved as well as the
existence of finite limits of all derivatives of the pressure at $\mu$ going to the transition
line. The explicit form of asymptotics of the limiting values of the derivatives
$d^kp/d\mu^k\sim(k!)^{d/(d-1)}$ for real $\beta, \mu$ and large $k$ is found. It proves that the point of the first kind phase transition is an essentially singular point. Relation of the resut obtained to the properties of the system in metastable state is discussed.
Received: 05.12.1985
Citation:
S. N. Isakov, “Phase diagrams and singularity at the point of a phase transition of the first kind in lattice gas models”, TMF, 71:3 (1987), 426–440; Theoret. and Math. Phys., 71:3 (1987), 638–648
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https://www.mathnet.ru/eng/tmf4972 https://www.mathnet.ru/eng/tmf/v71/i3/p426
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Abstract page: | 363 | Full-text PDF : | 111 | References: | 58 | First page: | 1 |
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