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This article is cited in 6 scientific papers (total in 6 papers)
Thermodynamics and Hydrodynamics (Statistical Foundations): 2. Thermodynamic Equilibrium
G. A. Martynov Institute of Physical Chemistry, Russian Academy of Sciences
Abstract:
We show that the BBGKY hierarchy in thermodynamic equilibrium degenerates into an equilibrium hierarchy. In turn, the latter can be used to obtain both the fundamental system of equations describing the state of matter inside a correlation sphere of the radius $R\approx10^{-7}$cm and the canonical Gibbs distribution, which, according to the current concepts, describes the state of the entire macroscopic system. We show that the Gibbs distribution is indeed also local, i.e., describes the state of matter only inside the correlation sphere; in the thermostat surrounding this sphere, the Gibbs distribution degenerates into a constant. We state that these two approaches are equivalent to each other.
Keywords:
equilibrium BBGKY hierarchy, local approach, Gibbs distribution, Ornstein–Zernike equation, correlation sphere, thermostat.
Received: 26.11.2001 Revised: 19.02.2002
Citation:
G. A. Martynov, “Thermodynamics and Hydrodynamics (Statistical Foundations): 2. Thermodynamic Equilibrium”, TMF, 134:2 (2003), 325–336; Theoret. and Math. Phys., 134:2 (2003), 285–294
Linking options:
https://www.mathnet.ru/eng/tmf153https://doi.org/10.4213/tmf153 https://www.mathnet.ru/eng/tmf/v134/i2/p325
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Abstract page: | 540 | Full-text PDF : | 272 | References: | 76 | First page: | 1 |
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