Abstract:
Various approaches to the synthesis of rotaxanes and polyrotaxanes are considered. The principles employed in the design of highly organised structures comprising rod-shaped polymeric molecules, viz., macromolecular inclusion complexes, are discussed. In addition to the conventional (step-by-step) methodology which consists of polymerisation of monomers in the presence of macrocycles, molecular self-assembly is gaining an ever increasing significance. The main emphasis is laid on the preparation and characterisation of inclusion complexes which are based on cyclodextrins and linear synthetic polymers. The bibliography includes 138 references.
Received: 02.06.2000
Bibliographic databases:
Document Type:
Article
UDC:
541(49+64):547.55
Language: English
Original paper language: Russian
Citation:
I. G. Panova, I. N. Topchieva, “Rotaxanes and polyrotaxanes. Their synthesis and the supramolecular devices based on them”, Usp. Khim., 70:1 (2001), 28–51; Russian Chem. Reviews, 70:1 (2001), 23–44
Linking options:
https://www.mathnet.ru/eng/rcr734
https://doi.org/10.1070/RC2001v070n01ABEH000608
https://www.mathnet.ru/eng/rcr/v70/i1/p28
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