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This article is cited in 21 scientific papers (total in 21 papers)
Correlation analysis in the chemistry of free radicals
A. R. Cherkasova, M. Jonssonb, V. I. Galkina, R. A. Cherkasova a Department of Chemistry, Kazan State University
b Department of Chemistry, Royal Institute of Technology, Stockholm, Sweden
Abstract:
Published data now available on the use of correlation analysis in free-radical chemistry are discussed systematically. The scales of 'radical' σ-constants of substituents proposed previously are analysed. It is shown that none of them is applicable as a general scale because almost in all cases, it is impossible to separate correctly the proper radical and polar contributions to the overall effect of substituents. A new approach to the quantitative estimation of the relationship between the structure and reactivity of molecules in free-radical processes called r–2-analysis is proposed. The bibliography includes 238 references.
Received: 02.02.2000
Citation:
A. R. Cherkasov, M. Jonsson, V. I. Galkin, R. A. Cherkasov, “Correlation analysis in the chemistry of free radicals”, Usp. Khim., 70:1 (2001), 3–27; Russian Chem. Reviews, 70:1 (2001), 1–22
Linking options:
https://www.mathnet.ru/eng/rcr733https://doi.org/10.1070/RC2001v070n01ABEH000574 https://www.mathnet.ru/eng/rcr/v70/i1/p3
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