Abstract:
The review presents new data on the preparation of aryl derivatives of thallium(III) and their application in organic synthesis, which is based on the possibility of the selective introduction of an organic group into an aromatic ring by replacing the thallium atom in arylthallium compounds. Processes involving the modification of aromatic compounds in the presence of thallium salts are also considered. The probable mechanisms of the reactions occurring in such processes are discussed. The bibliography includes 97 references.
Bibliographic databases:
Document Type:
Article
UDC:
577.174; 547.433
Language: English
Original paper language: Russian
Citation:
A. Ya. Usyatinskii, V. I. Bregadze, “Aryl Derivatives of Thallium(III): Preparation and Use in Organic Synthesis”, Usp. Khim., 57:11 (1988), 1840–1866; Russian Chem. Reviews, 57:11 (1988), 1054–1068
Linking options:
https://www.mathnet.ru/eng/rcr3929
https://doi.org/10.1070/RC1988v057n11ABEH003411
https://www.mathnet.ru/eng/rcr/v57/i11/p1840
This publication is cited in the following 2 articles:
Vsevolod V. Rostovtsev, Handbook of C–H Transformations, 2005, 99
N. F. Goldshleger, A. P. Moravskii, Russian Chem. Reviews, 63:2 (1994), 125–138