Abstract:
The principal methods for the investigation of outer-sphere interactions in solutions of labile inner-sphere complexes are arranged systematically and analysed. The modern views on the thermodynamics and structure of outer-sphere complexes are discussed and the reliability of certain hypotheses and models is examined from the standpoint of the comparison of the results of different experimental methods and theoretical ideas. A number of features of the outer-sphere interaction in solutions are formulated in relation to outer-sphere associated species formed by 3d metals, using certain data about the associated species of s, p, and f metals as well as outer-sphere associated species of inert complex cations. The bibliography includes 203 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.49:541.571.53
Language: English
Original paper language: Russian
Citation:
Yu. A. Makashev, V. E. Mironov, “Outer-sphere Interactions in Solutions of Labile Complexes”, Usp. Khim., 49:7 (1980), 1188–1213; Russian Chem. Reviews, 49:7 (1980), 631–644
Linking options:
https://www.mathnet.ru/eng/rcr3231
https://doi.org/10.1070/RC1980v049n07ABEH002493
https://www.mathnet.ru/eng/rcr/v49/i7/p1188
This publication is cited in the following 4 articles:
S. A. Ukhov, Fine Chem. Tech., 14:3 (2019), 5
O. Berkh, A. Khatchatouriants, N. Eliaz, E. Gileadi, J. Electrochem. Soc., 161:12 (2014), D632
Savvin S. Shtykov S. Mikhailova A., Uspekhi Khimii, 75:4 (2006), 380–389
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