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Russian Chemical Reviews, 1979, Volume 48, Issue 9, Pages 814–827
DOI: https://doi.org/10.1070/RC1979v048n09ABEH002414
(Mi rcr3161)
 

This article is cited in 45 scientific papers (total in 45 papers)

Progress in the Theory of Acids and Bases

M. I. Kabachnik
Abstract: Published data on the acid–base properties of organic substances in the gaseous phase have been reviewed. The proton affinity (PA) of bases is taken as the enthalpy of the gaseous reaction M + H+ → MH+, with the opposite sign, and the basic strength of the bases (GB) is taken as the change in the standard free energy of this reaction (again with opposite sign). Correspondingly, the acidity in the gaseous phase is taken to be the enthalpy of the reaction AH → A + H+ or the change in the standard free energy of this reaction.
The dependence of the acid strength and base strength in the gaseous phase on the structures of the molecules of the acids and bases has been examined, and the lack of agreement between the observed facts and the classical electronic interpretation based on the inductive and mesomeric effects of the groups has been discussed. Attention has been drawn to the change in the acid–base properties of organic molecules on going from the gaseous to the liquid phase, and the energetic effects of the solvation of the molecules and ions have been examined.
The bibliography contains 78 references.
Bibliographic databases:
Document Type: Article
UDC: 541.124.7
Language: English
Original paper language: Russian


Citation: M. I. Kabachnik, “Progress in the Theory of Acids and Bases”, Usp. Khim., 48:9 (1979), 1523–1547; Russian Chem. Reviews, 48:9 (1979), 814–827
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  • https://www.mathnet.ru/eng/rcr/v48/i9/p1523
  • This publication is cited in the following 45 articles:
    1. N. F. Lazareva, I. M. Lazarev, Russ Chem Bull, 73:4 (2024), 761  crossref
    2. Rodrigo M. Pontes, Computational and Theoretical Chemistry, 1140 (2018), 63  crossref
    3. Lazareva N.F. Nikonov A.Yu., Russ. Chem. Bull., 66:7 (2017), 1138–1162  crossref  isi
    4. D. V. Valeev, V. A. Bychinskii, K. V. Chudnenko, Russ. J. Inorg. Chem., 60:11 (2015), 1427  crossref
    5. V. P. Andreev, P. S. Sobolev, D. O. Zaitsev, V. A. Tafeenko, Russ J Gen Chem, 84:2 (2014), 320  crossref
    6. Raman Tandon, Tobias A. Nigst, Hendrik Zipse, Eur J Org Chem, 2013:24 (2013), 5423  crossref
    7. P. B. Vorobyev, A. P. Serebryanskaya, Russ J Gen Chem, 82:12 (2012), 1987  crossref
    8. I. B. Dzvinchuk, A. M. Nesterenko, V. V. Polovinko, A. B. Ryabitskii, M. O. Lozinskii, Chem Heterocycl Comp, 47:8 (2011), 953  crossref
    9. N. I. Selivanov, L. G. Samsonova, V. Ya. Artyukhov, T. N. Kopylova, Russ Phys J, 54:5 (2011), 601  crossref
    10. Solvents and Solvent Effects in Organic Chemistry, 2010, 587  crossref
    11. V. P. Andreev, Chem Heterocycl Comp, 46:2 (2010), 184  crossref
    12. Nataliya F. Lazareva, Tamara I. Vakul'skaya, Igor M. Lazarev, J of Physical Organic Chem, 22:2 (2009), 144  crossref
    13. E. G. Tarakanova, O. Yu. Tsoi, G. V. Yukhnevich, I. S. Kislina, N. B. Librovich, Russian Journal of Physical Chemistry B, 2:1 (2008), 13  crossref
    14. G. A. Zenkovets, G. N. Kryukova, Kinet Catal, 49:1 (2008), 127  crossref
    15. G. M. Maksimov, G. S. Litvak, A. A. Budneva, E. A. Paukshtis, A. N. Salanov, V. A. Likholobov, Kinet Catal, 47:4 (2006), 564  crossref
    16. I. A. Kuznetsova, M. N. Rodnikova, N. A. Chumaevskii, N. A. Minaeva, Russ. J. Inorg. Chem., 51:3 (2006), 504  crossref
    17. A. N. Pankratov, Chem Heterocycl Compd, 41:3 (2005), 340  crossref
    18. A. N. Pankratov, B. I. Drevko, Chem Heterocycl Compd, 41:9 (2005), 1105  crossref
    19. C.H. Bamford, Comprehensive Chemical Kinetics, 41, Oxoacidity: Reactions of oxo-compounds in ionic Solvents, 2005, 1  crossref
    20. A. N. Pankratov, S. S. Khmelev, J Struct Chem, 46:3 (2005), 404  crossref
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