Abstract:
The structure of organic compounds of arsenic is considered. Data are presented on the configurational stability and the energy of the inversion barrier in asymmetric arsines. The methods of synthesis of tertiary asymmetric arsenic compounds are surveyed. The results of the separation of asymmetric arsines into optically active isomers and the mechanisms of their transformation as well as the influence of substituents in the benzene ring on the optical activity are described. An analogy is drawn between the stereochemistries of organophosphorus and organoarsenic compounds. The bibliography includes 220 references.
Bibliographic databases:
Document Type:
Article
UDC:
547.242.541.63
Language: English
Original paper language: Russian
Citation:
F. D. Yambushev, V. I. Savin, “The Stereochemistry of Organoarsenic Compounds”, Usp. Khim., 48:6 (1979), 1093–1118; Russian Chem. Reviews, 48:6 (1979), 582–595
Linking options:
https://www.mathnet.ru/eng/rcr3143
https://doi.org/10.1070/RC1979v048n06ABEH002346
https://www.mathnet.ru/eng/rcr/v48/i6/p1093
This publication is cited in the following 6 articles:
Alexander L. Bond, Jennifer L. Lavers, Arch Environ Contam Toxicol, 61:2 (2011), 318
Sabina C. Grund, Kunibert Hanusch, Hans Uwe Wolf, Ullmann's Encyclopedia of Industrial Chemistry, 2008
Contact us: