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Russian Chemical Reviews, 1978, Volume 47, Issue 3, Pages 247–264
DOI: https://doi.org/10.1070/RC1978v047n03ABEH002216
(Mi rcr3040)
 

This article is cited in 29 scientific papers (total in 29 papers)

The Photochemical and Radiation-chemical Stability of Molecules. Unimolecular Reactions Involving the Abstraction of a Hydrogen Atom

V. G. Plotnikov, A. A. Ovchinnikov

Karpov Institute of Physical Chemistry, Moscow
Abstract: The ways in which electronically excited molecular systems are deactivated are examined, a theory of the non-adiabatic and predissociation mechanisms for the decomposition of molecular systems with elimination of a hydrogen atom is described, and the isotope effect in this reaction is discussed and compared with experimental data. The photochemical stability of molecules of different classes, radical-cations, and radicals is explained on the basis of the theoretical results. The evolution of atomic hydrogen (formation of radicals) in low-temperature radiation-chemical experiments is associated with the position of the lowest triplets state of the molecules, their ionisation potentials, the polarity of the medium, and the energies of the C–H bonds in the radical-cations.
The bibliography includes 95 references.
Bibliographic databases:
Document Type: Article
UDC: 541.141.541.15
Language: English
Original paper language: Russian


Citation: V. G. Plotnikov, A. A. Ovchinnikov, “The Photochemical and Radiation-chemical Stability of Molecules. Unimolecular Reactions Involving the Abstraction of a Hydrogen Atom”, Usp. Khim., 47:3 (1978), 444–476; Russian Chem. Reviews, 47:3 (1978), 247–264
Linking options:
  • https://www.mathnet.ru/eng/rcr3040
  • https://doi.org/10.1070/RC1978v047n03ABEH002216
  • https://www.mathnet.ru/eng/rcr/v47/i3/p444
  • This publication is cited in the following 29 articles:
    1. Yu M. Boiko, V. A. Zakrevskii, V. A. Pakhotin, N. T. Sudar, Colloid Polym Sci, 297:6 (2019), 831  crossref
    2. V. A. Kuzmin, V. A. Volnukhin, A. E. Egorov, O. N. Klimovich, A. A. Kostyukov, T. D. Nekipelova, E. N. Khodot, V. V. Shakhmatov, A. V. Shevelev, A. B. Shibaeva, A. A. Shtil, Russ. J. Phys. Chem. B, 13:6 (2019), 893  crossref
    3. V. A. Smirnov, N. N. Denisov, V. G. Plotnikov, M. V. Alfimov, High Energy Chem, 50:1 (2016), 51  crossref
    4. Komarova K.G. Sakipov S.N. Plotnikov V.G. Smirnov V.A. Alfimov M.V., High Energy Chem., 48:6 (2014), 359–362  crossref  isi
    5. V. G. Plotnikov, Russ. J. Phys. Chem., 88:11 (2014), 1849  crossref
    6. Yuri M. Boiko, Vladimir A. Zakrevskii, Vladimir A. Pakhotin, The Journal of Adhesion, 90:7 (2014), 596  crossref
    7. V. A. Smirnov, N. N. Denisov, M. V. Alfimov, Nanotechnol Russia, 8:1-2 (2013), 1  crossref
    8. Panayiotis C. Varras, Antonios K. Zarkadis, J. Phys. Chem. A, 116:5 (2012), 1425  crossref
    9. V. G. Plotnikov, V. A. Smirnov, M. V. Alfimov, High Energy Chem, 43:4 (2009), 241  crossref
    10. Vladimir Skurat, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 208 (2003), 27  crossref
    11. Phys. Usp., 45:10 (2002), 1019–1050  mathnet  crossref  crossref  adsnasa  isi
    12. S. V. Nesterov, O. Yu. Panov, J Radioanal Nucl Chem, 231:1-2 (1998), 87  crossref
    13. M. Ya. Mel'nikov, International Journal of Polymeric Materials, 32:1-4 (1996), 1  crossref
    14. G. Móger, M. Győr, Journal of Photochemistry and Photobiology A: Chemistry, 59:1 (1991), 37  crossref
    15. G. Móger, M. Győr, T. Vidóczy, D. Gál, Journal of Photochemistry and Photobiology B: Biology, 8:1 (1990), 97  crossref
    16. J. Kuruc, V. E. Zubarev, L. T. Bugaenko, F. Macášek, Journal of Radioanalytical and Nuclear Chemistry Letters, 127:1 (1988), 37  crossref
    17. G. Földiák, L. Wojnárovits, International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry, 32:3 (1988), 335  crossref
    18. Ya. N. Malkin, Sh. Ruziev, N. O. Pirogov, V. A. Kuz'min, Russ Chem Bull, 36:1 (1987), 51  crossref
    19. S. P. Makarov, Ya. N. Malkin, Russ Chem Bull, 34:4 (1985), 697  crossref
    20. V.G. Plotnikov, Radiation Physics and Chemistry (1977), 26:5 (1985), 519  crossref
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