Abstract:
Ion–molecule reactions initiated by the β-decomposition of tritium in various compounds are examined and a systematic account is given. The theoretical and experimental foundations of the radiochemical method for the investigation of this important type of chemical interactions are described. The ion–molecule reactions investigated are combined in two groups: the reactions of the ions HeT+ and the reactions of carbonium ions. Conclusions concerning the reactivity of the intermediate species, the mechanisms of their interaction with various substances, and the prospects for the utilisation of the radiochemical method of investigating ion–molecule reactions are reached on the basis of the experimental results presented. The bibliography includes 162 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.121/128+541.28+546.11.3
Language: English
Original paper language: Russian
Citation:
G. P. Akulov, “Ion–Molecule Reactions Initiated by the β-Decomposition of Tritium in Tritiated Compounds”, Usp. Khim., 45:11 (1976), 1970–1999; Russian Chem. Reviews, 45:11 (1976), 1008–1023
Linking options:
https://www.mathnet.ru/eng/rcr2930
https://doi.org/10.1070/RC1976v045n11ABEH002747
https://www.mathnet.ru/eng/rcr/v45/i11/p1970
This publication is cited in the following 6 articles:
A. B. Sazonov, A. A. Ostroverkhova, E. P. Magomedbekov, Russ. J. Phys. Chem., 81:12 (2007), 1997
F. Bernardi, F. Grandinetti, A. Guarino, M.A. Robb, Chemical Physics Letters, 153:4 (1988), 309
Fulvio Cacace, Structure/Reactivity and Thermochemistry of Ions, 1987, 467
Fulvio Cacace, Treatise on Heavy-Ion Science, 1985, 61
Fulvio Cacace, Maurizio Speranza, Alfred P. Wolf, Richard Ehrenkaufer, Labelled Comp Radiopharmac, 19:8 (1982), 905
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