Abstract:
Certain fundamental concepts and definitions in the thermodynamic theory of the platinum electrode are examined and the concepts of the zero total charge and zero free charge potentials and methods for determination of these quantities are discussed. Data indicating charge transfer in chemisorption processes are analysed and a thermodynamic approach to the analysis of this phenomenon is considered. The influence of the pH of the solution on the structure of the platinum metal–electrolyte solution interface is examined. The bibliography includes 186 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.135.52-183
Language: English
Original paper language: Russian
Citation:
O. A. Petrii, “Adsorption Phenomena on Platinum Group Metal Electrodes”, Usp. Khim., 44:11 (1975), 2048–2060; Russian Chem. Reviews, 44:11 (1975), 973–981
Linking options:
https://www.mathnet.ru/eng/rcr2846
https://doi.org/10.1070/RC1975v044n11ABEH002403
https://www.mathnet.ru/eng/rcr/v44/i11/p2048
This publication is cited in the following 4 articles:
ACS In Focus, Electrochemistry Fundamentals, 2023
M. A. Akhmedov, K. O. Ibragimova, Sh. Sh. Khidirov, Russ J Electrochem, 56:5 (2020), 396