Abstract:
Methods of obtaining nitroxyl radicals by the dehydrogenation of hydroxylamines, oxidation of amines, reduction of nitro and nitroso-compounds and radical addition to nitrones are considered. Problems of the stability of nitroxyl radicals and their reactivity are discussed – redox reactions, radical reactions, complex formation, and reaction without use of the unpaired electron. There is a bibliography of 283 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.515.546.17
Language: English
Original paper language: Russian
Citation:
E. G. Rozantsev, V. D. Sholle, “Progress in the Chemistry of Nitroxyl Radicals”, Usp. Khim., 40:3 (1971), 417–443; Russian Chem. Reviews, 40:3 (1971), 233–246
Linking options:
https://www.mathnet.ru/eng/rcr2433
https://doi.org/10.1070/RC1971v040n03ABEH001915
https://www.mathnet.ru/eng/rcr/v40/i3/p417
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