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This article is cited in 24 scientific papers (total in 24 papers)
Correlation Equations in Free-radical Reactions
I. B. Afanas'ev NII Vitamins, Moscow
Abstract:
This review deals with the methods of correlation analysis which have been applied to studies of the kinetics of free-radical reactions. It discusses the use of the Hammett and the Taft equation, of the Alfrey–Price scheme, of the Bamford equation, and also the correlations with quantum-mechanical parameters and various additive empirical methods. Polar and resonance effects in free-radical reactions are quantitatively separated by a two-parameter scheme based on the Taft equation. The relationship between the structure of the transition state and the reactivity of the free radicals is considered. 265 references.
Citation:
I. B. Afanas'ev, “Correlation Equations in Free-radical Reactions”, Usp. Khim., 40:3 (1971), 385–416; Russian Chem. Reviews, 40:3 (1971), 216–232
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https://www.mathnet.ru/eng/rcr2432https://doi.org/10.1070/RC1971v040n03ABEH001914 https://www.mathnet.ru/eng/rcr/v40/i3/p385
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