Abstract:
This review deals with the methods of correlation analysis which have been applied to studies of the kinetics of free-radical reactions. It discusses the use of the Hammett and the Taft equation, of the Alfrey–Price scheme, of the Bamford equation, and also the correlations with quantum-mechanical parameters and various additive empirical methods. Polar and resonance effects in free-radical reactions are quantitatively separated by a two-parameter scheme based on the Taft equation. The relationship between the structure of the transition state and the reactivity of the free radicals is considered. 265 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.127
Language: English
Original paper language: Russian
Citation:
I. B. Afanas'ev, “Correlation Equations in Free-radical Reactions”, Usp. Khim., 40:3 (1971), 385–416; Russian Chem. Reviews, 40:3 (1971), 216–232
Linking options:
https://www.mathnet.ru/eng/rcr2432
https://doi.org/10.1070/RC1971v040n03ABEH001914
https://www.mathnet.ru/eng/rcr/v40/i3/p385
This publication is cited in the following 24 articles:
David A. Cagan, Daniel Bím, Nathanael P. Kazmierczak, Ryan G. Hadt, ACS Catal., 14:11 (2024), 9055
Stavros K. Kariofillis, Abigail G. Doyle, Acc. Chem. Res., 54:4 (2021), 988
Laura K. G. Ackerman, Jesus I. Martinez Alvarado, Abigail G. Doyle, J. Am. Chem. Soc., 140:43 (2018), 14059
Vivian S. Lin, Matthew Grandbois, Kristopher McNeill, Environ. Sci. Technol., 51:16 (2017), 9033
V. A. Lopyrev, L. I. Larina, L. Kh. Baumane, E. F. Shibanova, R. A. Gavar, S. M. Ponomareva, T. I. Vakul'skaya, Ya. P. Stradyn', Chem Heterocycl Compd, 20:9 (1984), 1021
I. B. Afanas'ev, Int J of Chemical Kinetics, 13:2 (1981), 173
Jacques Fossey, Daniel Lefort, Tetrahedron, 36:8 (1980), 1023
Hiroyuki Shinohara, Akira Imamura, Takahiro Masuda, Masaharu Kondo, Bulletin of the Chemical Society of Japan, 52:10 (1979), 2801
M. G. Katz, L. A. Rajbenbach, Int J of Chemical Kinetics, 10:9 (1978), 955
A. Pross, Advances in Physical Organic Chemistry, 14, Advances in Physical Organic Chemistry Volume 14, 1977, 69
I. B. Afanas'Ev, Int J of Chemical Kinetics, 7:6 (1975), 857
Contact us: