Abstract:
Excperimental data on the effect of viscosity on the kinetics of elementary chernical reactions of free radicals in solid matrices and viscous solutions are analysed. The dynamic effects in EPR spectroscopy are used for the simultaneous investigation of molecular and chemical dynamics. The intramolecular transformations in free radicals and the spin exchange in biradicals are considered. It is shown that the rates of such intramolecular reactions are controlled by the molecular dynamics of the chemical cage. The bibliography includes 58 references.
Received: 18.01.1993
Bibliographic databases:
Document Type:
Article
UDC:
541.515:541.124
Language: English
Original paper language: Russian
Citation:
R. R. Rakhimov, A. I. Prokof'ev, Ya. S. Lebedev, “Relation between molecular and chemical dynamics for elementary radical reactions in viscous media”, Usp. Khim., 62:6 (1993), 547–565; Russian Chem. Reviews, 62:6 (1993), 509–526
Linking options:
https://www.mathnet.ru/eng/rcr1105
https://doi.org/10.1070/RC1993v062n06ABEH000030
https://www.mathnet.ru/eng/rcr/v62/i6/p547
This publication is cited in the following 8 articles:
Alexey V. Bogdanov, Andrey Kh. Vorobiev, Chemical Physics Letters, 506:1-3 (2011), 46
K. U. Ingold, Gino A. DiLabio, Can. J. Chem., 89:2 (2011), 235
Rakhim R. Rakhimov, Tamika N. Hawkins, Jimmy S. Hwang, Alexander I. Prokof'ev, Aleksey I. Aleksandrov, J. Phys. Chem. A, 107:33 (2003), 6345
A. I. Prokof'ev, Russian Chem. Reviews, 68:9 (1999), 727–736
Rakhim R. Rakhimov, Nikolas P. Benetis, Anders Lund, Jimmy S. Hwang, Alexander I. Prokof'ev, Yakov S. Lebedev, Chemical Physics Letters, 255:1-3 (1996), 156
R. R. Rakhimov, A. I. Prokof'ev, Ya. S. Lebedev, Russ Chem Bull, 43:3 (1994), 368
Ya. S. Lebedev, Appl. Magn. Reson., 7:2-3 (1994), 339
S. S. Ivanchev, V. N. Pavlyuchenko, Russian Chem. Reviews, 63:8 (1994), 667–684
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