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This article is cited in 6 scientific papers (total in 6 papers)
Phosphorus-containing nucleophiles in reactions with polyfluorinated organic compounds
G. G. Furin Novosibirsk Institute of Organic Chemistryof the Siberian Branch of Russian Academy of Sciences
Abstract:
The review presents a compilation of new expelimental data on the reactions of phosphorus-containing nucleophiles [triphenylphosphine, trialkylphosphines, trialkyl phosphites, phosphorus tris(diethylamide), etc.] with perfluorinated olefins and aromatic and heterocyclic compounds, leading to substances both with and without a phosphorus atom. It is shown that the interaction of phosphorus tris(diethylamide) and trialkylphosphines with organic polyfluoro-compounds and perfluoroolefins leads to the formation of phosphoranes, the decomposition of which is accompanied by the generation of aryl and alkenyl anions. The reactions of these anions with C-electrophiles and compounds containing mobile halogen atoms are examined. In addition, the pathways in the Arbuzov reaction involving a series of unsaturated perfluorinated compounds are analysed. Possible applications of these reactions in organic synthesis are demonstrated. The bibliography includes 120 references.
Received: 01.07.1992
Citation:
G. G. Furin, “Phosphorus-containing nucleophiles in reactions with polyfluorinated organic compounds”, Usp. Khim., 62:3 (1993), 267–283; Russian Chem. Reviews, 62:3 (1993), 243–259
Linking options:
https://www.mathnet.ru/eng/rcr1091https://doi.org/10.1070/RC1993v062n03ABEH000016 https://www.mathnet.ru/eng/rcr/v62/i3/p267
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