Abstract:
The existing theoretical ideas concerning the intramolecular interaction in organic compounds of silicon-subgroup elements are examined in relation to the results of experimental studies. It is shown that the overall resonance effect of organoelement substituents includes acceptor (joint influence of unoccupied nd and antibonding σ* orbitals) and donor (σ,π conjugation, σ,π* conjugation, and σ,n conjugation) components. The relative contributions of these components to the resonance effect are analysed as a function of the type of central element, the organic groups linked to it, and the reaction centre. The bibliography includes 161 references.
Bibliographic databases:
Document Type:
Article
UDC:
541.65:547.1'3
Language: English
Original paper language: Russian
Citation:
A. N. Egorochkin, “Conjunction in organic compounds of silicon-subgroup elements”, Usp. Khim., 61:6 (1992), 1092–1113; Russian Chem. Reviews, 61:6 (1992), 600–612
Linking options:
https://www.mathnet.ru/eng/rcr1036
https://doi.org/10.1070/RC1992v061n06ABEH000987
https://www.mathnet.ru/eng/rcr/v61/i6/p1092
This publication is cited in the following 27 articles:
Rui Wei, Xin-Feng Wang, Chaopeng Hu, Liu Leo Liu, Chem. Commun., 60:72 (2024), 9793
O. V. Kuznetsova, A. N. Egorochkin, N. M. Khamaletdinova, Russ J Gen Chem, 91:12 (2021), 2352
Nikolai L. Ermolaev, Ilya V. Lenin, Georgii K. Fukin, Andrei S. Shavyrin, Mikhail A. Lopatin, Olga V. Kuznetsova, Boris A. Andreev, Denis I. Kryzhkov, Stanislav K. Ignatov, Evgeny P. Chuhmanov, Nadezhda T. Berberova, Konstantin P. Pashchenko, Journal of Organometallic Chemistry, 797 (2015), 83
Alexey N. Egorochkin, Olga V. Kuznetsova, Nadiya M. Khamaletdinova, Lada G. Domratcheva-Lvova, Journal of Organometallic Chemistry, 696:10 (2011), 2199
Mikhail G. Voronkov, Alexey N. Egorochkin, Patai's Chemistry of Functional Groups, 2009
A.N. Egorochkin, O.V. Kuznetsova, N.M. Khamaletdinova, L.G. Domratcheva-Lvova, G.A. Domrachev, Journal of Electron Spectroscopy and Related Phenomena, 171:1-3 (2009), 47
Alexey N. Egorochkin, Mikhail G. Voronkov, Olga V. Kuznetsova, Olga V. Novikova, Journal of Organometallic Chemistry, 693:2 (2008), 181
D. A. de Vekki, V. M. Uvarov, A. N. Reznikov, N. K. Skvortsov, Russ Chem Bull, 57:2 (2008), 349
V. V. Zhuikov, Russ J Electrochem, 36:2 (2000), 117
A. N. Egorochkin, M. G. Voronkov, S. E. Skobeleva, T. G. Mushtina, O. V. Zderenova, Russ Chem Bull, 49:2 (2000), 256
A. N. Egorochkin, S. E. Skobeleva, T. G. Mushtina, Russ Chem Bull, 47:8 (1998), 1436
A. N. Egorochkin, S. E. Skobeleva, T. G. Mushtina, Russ Chem Bull, 47:12 (1998), 2352
A. N. Egorochkin, S. E. Skobeleva, T. G. Mushtina, E. T. Bogoradovsky, Russ Chem Bull, 47:8 (1998), 1526
A. N. Egorochkin, S. E. Skobeleva, T. G. Mushtina, E. T. Bogoradovsky, Russ Chem Bull, 46:1 (1997), 71
V. V. Jouikov, Russian Chem. Reviews, 66:6 (1997), 509–540
A. N. Egorochkin, S. E. Skobeleva, T. G. Mushtina, Russ Chem Bull, 46:1 (1997), 65
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