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Optics and Spectroscopy, 2018, Volume 125, Issue 2, Pages 209–217
DOI: https://doi.org/10.21883/OS.2018.08.46362.110-18
(Mi os933)
 

This article is cited in 2 scientific papers (total in 2 papers)

Spectroscopy of condensed matter

Investigation of the inductive-resonant interaction of water clusters in fluorapatite minerals using polarization IR and Raman spectroscopy

V. M. Zolotarev

National Research University of Information Technologies, Mechanics, and Optics, St. Petersburg, 197101, Russia
Full-text PDF (790 kB) Citations (2)
Abstract: Polarization studies of the vibrational spectra of clusters (Н$_{2}$О)$_{n}$ in samples of single-crystal fluorapatite of different deposits were carried out by infrared (IR) spectroscopy and Raman spectroscopy. The IR and Raman spectra were measured for two orthogonal directions of the external excitation field: parallel and perpendicular to the $c$-channels in fluorapatite single crystals. Interpretation of the interaction of the external electromagnetic field with clusters of water situated in microvoids and microcracks of the crystal with the structural groups of F $\dots$ HO of apatite is given in the framework of the dipole–dipole approximation. This interaction has an induction–resonance character (IR spectroscopy) caused by the transfer of vibrational excitation from the F $\dots$ HO groups to (Н$_{2}$О)$_{n}$ clusters. In the case of Raman spectroscopy, the induction character of the excitation of (Н$_{2}$О)$_{n}$ clusters takes place due to the transfer of electron excitation from the F $\dots$ HO groups.
Received: 18.04.2018
English version:
Optics and Spectroscopy, 2018, Volume 125, Issue 2, Pages 218–226
DOI: https://doi.org/10.1134/S0030400X18080246
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: V. M. Zolotarev, “Investigation of the inductive-resonant interaction of water clusters in fluorapatite minerals using polarization IR and Raman spectroscopy”, Optics and Spectroscopy, 125:2 (2018), 209–217; Optics and Spectroscopy, 125:2 (2018), 218–226
Citation in format AMSBIB
\Bibitem{Zol18}
\by V.~M.~Zolotarev
\paper Investigation of the inductive-resonant interaction of water clusters in fluorapatite minerals using polarization IR and Raman spectroscopy
\jour Optics and Spectroscopy
\yr 2018
\vol 125
\issue 2
\pages 209--217
\mathnet{http://mi.mathnet.ru/os933}
\crossref{https://doi.org/10.21883/OS.2018.08.46362.110-18}
\elib{https://elibrary.ru/item.asp?id=35270065}
\transl
\jour Optics and Spectroscopy
\yr 2018
\vol 125
\issue 2
\pages 218--226
\crossref{https://doi.org/10.1134/S0030400X18080246}
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  • https://www.mathnet.ru/eng/os/v125/i2/p209
  • This publication is cited in the following 2 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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    Optics and Spectroscopy Optics and Spectroscopy
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