N. F. Bunkin, A. A. Balashov, A. V. Shkirin, V. S. Gorelik, A. È. Primenko, I. I. Molchanov, M. T. Vu, N. G. Bolikov, I. S. Bereza, M. E. Astashev, S. V. Gudkov, V. A. Kozlov, “Investigation of deuterium substitution effects in a polymer membrane using IR Fourier spectrometry”, Optics and Spectroscopy, 125:3 (2018), 324–329; Optics and Spectroscopy, 125:3 (2018), 337

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Optics and Spectroscopy, 2018, Volume 125, Issue 3, Pages 324–329
DOI: https://doi.org/10.21883/OS.2018.09.46545.27-18 (Mi os904)

This article is cited in 5 scientific papers (total in 5 papers)

Spectroscopy of condensed matter

Investigation of deuterium substitution effects in a polymer membrane using IR Fourier spectrometry

N. F. Bunkin^a, A. A. Balashov^b, A. V. Shkirin^cd, V. S. Gorelik^ae, A. È. Primenko^a, I. I. Molchanov^a, M. T. Vu^a, N. G. Bolikov^a, I. S. Bereza^a, M. E. Astashev^f, S. V. Gudkov^cgh, V. A. Kozlov^b

^a Bauman State Technical University, Moscow, 105005, Russia
^b Scientific and Technological Center of Unique Instrumentation, Russian Academy of Sciences, Moscow, 117342, Russia
^c Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, 119991, Russia
^d National Research Nuclear University MEPhI, Moscow, 115409, Russia
^e Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991, Russia
^f Institute of Cell Biophysics, Russian Academy of Sciences, Pushchino, Moscow oblast, 142290, Russia
^g Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, 603022, Russia
^h Moscow Regional Scientific-Research Clinical Institute

Full-text PDF (467 kB) Citations (5)

DOI: https://doi.org/10.21883/OS.2018.09.46545.27-18

Abstract: Experiments on IR Fourier spectrometry of a Nafion polymer membrane swollen in water are described. The dynamics of Nafion swelling is studied in relation to the deuterium content in water. It has turned out that, if the polymer swells in waters with different deuterium contents, a considerable confinement effect is observed, which, in this case, manifests itself in that the transmittance of IR radiation of water that is enclosed within a region with a size of

\sim

$\sim$ 100

μ

$\mu$ m differs from that of water that is inside nanometer pores of the polymer membrane. In addition, the transmittance of Nafion swollen in water measured at a wavelength of

λ

$\lambda$ = 1.92

μ

$\mu$ m (spectral minimum) experiences a local minimum in the deuterium concentration range 10

^{2} < C <

$^2<C<$ 10

^{3}

$^3$ ppm, irrespective of the soaking time of the polymer in deuterated water. Finally, the effect of the deuterium substitution of the residual water present in the volume of the membrane has been revealed.

Funding agency	Grant number
Russian Foundation for Basic Research	17-02-00214 16-52-540001 15-02-07586
Ministry of Education and Science of the Russian Federation	02.a03.21.0005
Ministry of Science and Higher Education of the Russian Federation	МД-3811.2018.11 AAAA-A18-118021390190-1

Received: 29.01.2018
Revised: 24.04.2018

English version:
Optics and Spectroscopy, 2018, Volume 125, Issue 3, Pages 337–342
DOI: https://doi.org/10.1134/S0030400X18090072

Bibliographic databases:

Document Type: Article

Language: Russian

Citation: N. F. Bunkin, A. A. Balashov, A. V. Shkirin, V. S. Gorelik, A. È. Primenko, I. I. Molchanov, M. T. Vu, N. G. Bolikov, I. S. Bereza, M. E. Astashev, S. V. Gudkov, V. A. Kozlov, “Investigation of deuterium substitution effects in a polymer membrane using IR Fourier spectrometry”, Optics and Spectroscopy, 125:3 (2018), 324–329; Optics and Spectroscopy, 125:3 (2018), 337–342

Citation in format AMSBIB

\Bibitem{BunBalShk18}

\by N.~F.~Bunkin, A.~A.~Balashov, A.~V.~Shkirin, V.~S.~Gorelik, A.~\`E.~Primenko, I.~I.~Molchanov, M.~T.~Vu, N.~G.~Bolikov, I.~S.~Bereza, M.~E.~Astashev, S.~V.~Gudkov, V.~A.~Kozlov

\paper Investigation of deuterium substitution effects in a polymer membrane using IR Fourier spectrometry

\jour Optics and Spectroscopy

\yr 2018

\vol 125

\issue 3

\pages 324--329

\mathnet{http://mi.mathnet.ru/os904}

\crossref{https://doi.org/10.21883/OS.2018.09.46545.27-18}

\elib{https://elibrary.ru/item.asp?id=36905221}

\transl

\jour Optics and Spectroscopy

\yr 2018

\vol 125

\issue 3

\pages 337--342

\crossref{https://doi.org/10.1134/S0030400X18090072}

Linking options:

https://www.mathnet.ru/eng/os904

https://www.mathnet.ru/eng/os/v125/i3/p324

This publication is cited in the following 5 articles:

N.F. Bunkin, S.V. Bashkin, S.V. Gudkov, M.S. Kiryanova, V.A. Kozlov, “Non-Stationarity Effects in Polymer Membrane Swelling as Studied by Infrared Fourier Spectrometry Technique”, HoBMSTU.SNS, 2022, no. 1 (100), 122
N. F. Bunkin, V. A. Kozlov, M. S. Kir'yanova, R. S. Safronenkov, P. N. Bolotskova, V. S. Gorelik, Y. Juraev, L. M. Sabirov, A. È. Primenko, M. T. Vu, “A Fourier ir spectroscopy study of the effects of unsteadiness on the process of swelling of polymeric membranes”, Optics and Spectroscopy, 129:4 (2021), 460–470
P. N. Bolotskova, N. F. Bunkin, V. A. Kozlov, T. Yu. Komkova, M. S. Kir'yanova, R. S. Safronenkov, M. T. Vu, “The Role of Shaking of a Liquid Sample in the Dynamics of Polymer Membrane Swelling: A Cell of Limited Volume”, Phys. Wave Phen., 29:2 (2021), 114
N.F. Bunkin, S.V. Bashkin, Y.T. Juraev, R.S. Safronenkov, V.A. Kozlov, “Rheological Effects on Swelling of Polymer Membranes in Water”, HoBMSTU.SNS, 2020, no. 6 (93), 36
N. F. Bunkin, V. A. Kozlov, M. S. Kiryanova, A. A. Pavlenko, R. S. Safronenkov, A. V. Shkirin, N. N. Shusharina, “Rheological Effects of Polymer Membrane Swelling in Water and Their Dependence on Isotopic Composition”, Phys. Wave Phen., 28:2 (2020), 182

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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