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Spectroscopy and physics of atoms and molecules
On double-valued wave functions in the description of intramolecular coordinate motions
A. V. Burenin Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod, 603950, Russia
Abstract:
It is shown that the appearance of double-valued wave functions in constructing the discrete-spectrum classification of coordinate motions in molecules with a linear core and two identical tops using the CNPI-group methods is the consequence of a physically incorrect determination of the action of symmetry operations on variables of a configuration space of the molecule.
Received: 14.05.2018
Citation:
A. V. Burenin, “On double-valued wave functions in the description of intramolecular coordinate motions”, Optics and Spectroscopy, 125:3 (2018), 318–323; Optics and Spectroscopy, 125:3 (2018), 331–336
Linking options:
https://www.mathnet.ru/eng/os903 https://www.mathnet.ru/eng/os/v125/i3/p318
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Statistics & downloads: |
Abstract page: | 45 | Full-text PDF : | 14 |
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