Abstract:
Transparent ZnO–MgO–Ag2O coatings are formed on glasses by the polymer–salt method, and the optical properties of these coatings are studied. The optical properties of the films are studied by optical spectroscopy and photoluminescence. The structure of the oxide coatings is studied by X-ray diffraction analysis and scanning electron microscopy. It is found that an increase in the silver concentration in the coatings leads to a decrease in the band gap width of the material. It is shown that the films are characterized by a high transparency in the visible spectral region and can generate singlet oxygen under action of UV radiation (370 nm) and blue light (405 nm).
Keywords:
photocatalyst, singlet oxygen, polymer–salt method, band gap width, X-ray diffraction analysis.
Citation:
S. K. Evstropiev, N. V. Nikonorov, V. M. Kiselev, A. S. Saratovskii, E. V. Kolobkova, “Transparent photoactive ZnO–MgO–Ag2O films on glasses”, Optics and Spectroscopy, 127:2 (2019), 292–299; Optics and Spectroscopy, 127:2 (2019), 314–321
This publication is cited in the following 6 articles:
A. S. Saratovskii, M. A. Girsova, K. Yu. Senchik, Yu. G. Zmitrichenko, L. N. Kurilenko, T. V. Antropova, “Fotogeneratsiya kisloroda kompozitom «poristoe steklo – ZnO» v vodnykh sredakh pri UF obluchenii”, Fizika i himiâ stekla, 50:3 (2024), 62
A. S. Saratovskii, M. A. Girsova, K. Yu. Senchik, Yu. G. Zmitrichenko, L. N. Kurilenko, T. V. Antropova, “Photogeneration of Oxygen by Composite “Porous Glass–ZnO” in an Aqueous Media under UV Irradiation”, Glass Phys Chem, 50:3 (2024), 240
K. Yu. Senchik, A. V. Karavaeva, A. S. Saratovskii, V. E. Agbemekh, G. V. Tochil'nikov, Yu. G. Zmitrichenko, S. K. Evstrop'ev, K. V. Dukel'skii, “Polymer-Salt Synthesis of Photoactive Bactericide ZnO–Ag and ZnO–SnO2–Ag Nanopowders and a Study of Their Structure and Properties”, Glass Phys Chem, 48:1 (2022), 75
N V Nikonorov, S K Evstropiev, A V Shelemanov, J F Podruhin, V M Kiselev, A V Karavaeva, “Design and fabrication of photoactive ZnO-MgO-Ag nanocomposites for medical and environmental applications”, J. Phys.: Conf. Ser., 2015:1 (2021), 012097
A. V. Svetlakova, M. Sanchez Mendez, E. S. Tuchina, A. N. Khodan, M. Traore, R. Azouani, A. Kanaev, V. V. Tuchin, “Study of the photocatalytic antimicrobial activity of nanocomposites based on TiO$_{2}$–Al$_{2}$O$_{3}$ under the action of LED radiation (405 nm) on staphylococci”, Optics and Spectroscopy, 129:8 (2021), 846–850
S. K. Evstrop'ev, N. V. Nikonorov, A. S. Saratovskii, D. P. Danilovich, “The effect of UV irradiation on the formation of silver molecular clusters and their stabilization in solutions and composite and oxide coatings”, Optics and Spectroscopy, 128:6 (2020), 707–712