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Optics and Spectroscopy, 2021, Volume 129, Issue 2, Pages 232–237
DOI: https://doi.org/10.21883/OS.2021.02.50563.220-20 (Mi os197) 		 
This article is cited in 7 scientific papers (total in 7 papers)

UV, IR, and terahertz optics

Study of the features of water film formation on montmorillonite and kaolinite surfaces by infrared spectroscopy

T. F. Nazdrachevaa, A. V. Kukharskiib, A. S. Kasprzhitskyc, G. Lazorenkoc, V. Yavnac, A. G. Kochurc

a Southern Federal University, Rostov-on-Don
b Skolkovo Institute of Science and Technology, Moscow, Russia
c Rostov State Transport University
Full-text PDF (817 kB) Citations (7)
DOI: https://doi.org/10.21883/OS.2021.02.50563.220-20
Abstract: Kaolinite (KGa-1b) and montmorillonite (STx-1b) reference samples were studied by infrared spectroscopy at various water contents. The spectral features reflecting the formation of water layers on the basal surfaces of individual minerals have been studied. Experimental studies were carried out by the Attenuated Total Reflection (ATR) Fourier Transform Infrared (FTIR) spectroscopy. The analysis of the composition of the wet samples was carried out by decomposing the experimental spectra into the spectrum of H2O and minerals in the air-dry condition. The obtained dependences of the participation coefficients of the basic spectra on humidity are compared with the results of measurements in the microwave range and make it possible to investigate the integral features of the formation of a water layer on mineral particles and to predict the plasticity of clays. The anomalous position of the maximum and the half-width of the stretching vibrational modes of water molecules at low water content have been established.
Keywords: Kaolinite, montmorillonite, clay minerals, hydration, infrared spectroscopy.
Funding agency Grant number
Ministry of Education and Science of the Russian Federation ВЧ-23
The work was carried out according to the state task of the Federal Agency for Railway Transport (Roszheldor Protocol no. VCh-23 dated 15.04.2020).
Received: 28.08.2020
Revised: 06.10.2020
Accepted: 14.10.2020
English version:
Optics and Spectroscopy, 2021, Volume 129, Issue 2, Pages 270–275
DOI: https://doi.org/10.1134/S0030400X21020107
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: T. F. Nazdracheva, A. V. Kukharskii, A. S. Kasprzhitsky, G. Lazorenko, V. Yavna, A. G. Kochur, “Study of the features of water film formation on montmorillonite and kaolinite surfaces by infrared spectroscopy”, Optics and Spectroscopy, 129:2 (2021), 232–237; Optics and Spectroscopy, 129:2 (2021), 270–275
Citation in format AMSBIB
\Bibitem{NazKukKas21}
\by T.~F.~Nazdracheva, A.~V.~Kukharskii, A.~S.~Kasprzhitsky, G.~Lazorenko, V.~Yavna, A.~G.~Kochur
\paper Study of the features of water film formation on montmorillonite and kaolinite surfaces by infrared spectroscopy
\jour Optics and Spectroscopy
\yr 2021
\vol 129
\issue 2
\pages 232--237
\mathnet{http://mi.mathnet.ru/os197}
\crossref{https://doi.org/10.21883/OS.2021.02.50563.220-20}
\elib{https://elibrary.ru/item.asp?id=45536711}
\transl
\jour Optics and Spectroscopy
\yr 2021
\vol 129
\issue 2
\pages 270--275
\crossref{https://doi.org/10.1134/S0030400X21020107}
Linking options:
  • https://www.mathnet.ru/eng/os197
  • https://www.mathnet.ru/eng/os/v129/i2/p232
    • This publication is cited in the following 7 articles:
    1. Juske Horita, Xinying Ling, Changjie Liu, Osamu Abe, Ryu Uemura, “Hydrogen and triple-oxygen isotope effects of water adsorption on KGa-2 kaolinite with implications for pedological separation of soil water”, Geochimica et Cosmochimica Acta, 2025  crossref
    2. Zhixin Chen, Yijie Wang, Liming Hu, “Thermal desorption mechanism of n-dodecane on unsaturated clay: Experimental study and molecular dynamics simulation”, Environmental Pollution, 323 (2023), 121228  crossref
    3. T. Nazdracheva, A. Morozov, V. Yavna, A. Kochur, “Data on FTIR spectra of the clays KGa-1b and STx-1b and their mixtures at different moistures”, Data in Brief, 42 (2022), 108282  crossref
    4. M. M. Filyak, A. G. Chetverikova, O. N. Kanygina, “Dielectric Properties of Finely Disperse Kaolinite Masses with Different Humidification”, Glass Ceram, 78:11-12 (2022), 458  crossref
    5. Tatiana Nazdracheva, Andrey Morozov, Victor Yavna, Andrei Kochur, “Study of hydration of kaolinite and montmorillonite mixture by IR spectroscopy”, Journal of Molecular Structure, 1250 (2022), 131871  crossref
    6. Andrey Morozov, Tatiana Nazdracheva, Andrei Kochur, Victor Yavna, “Effect of Sodium Chloride on the Profiles of the IR Spectrum Bands of Kaolinite at Moistures under Plastic Limit”, Crystals, 12:9 (2022), 1224  crossref
    7. Victor Yavna, Tatiana Nazdracheva, Andrey Morozov, Yakov Ermolov, Andrei Kochur, “Ab Initio Simulation of the IR Spectrum of Hydrated Kaolinite”, Crystals, 11:9 (2021), 1146  crossref
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