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This article is cited in 1 scientific paper (total in 1 paper)
Numerical simulation of oxidative regeneration of a spherical catalyst grain
I. M. Gubaydullina, E. E. Peskovab, O. S. Yazovtsevab, A. N. Zagoruikoc a Institute of Petrochemistry and Catalysis of the Russian Academy of Sciences, Ufa
b National Research Mordovia State University, Saransk
c Boreskov Institute of Catalysis SB RAS, Novosibirsk
Abstract:
The article is devoted to construction of a numerical algorithm for modeling the oxidative regeneration of a spherical catalyst grain The model is described by a nonlinear system of partial differential equations. The equations reflecting the dynamics of the components of the gas phase of the reaction are compiled based on the law of active masses
conservation. They take into account the diffusion of components into the pores of the
grain, the Stefan flow responsible for the movement of reaction products to the grain surface and the kinetic features of chemical reactions accompanying oxidative regeneration.
The equation corresponding to the change in the temperature of the catalyst grain includes heat transfer and heating of the grain due to exothermic reactions. The remaining
variables are used to account for changes in the qualitative and quantitative composition
of coke deposits. The numerical algorithm based on the integro-interpolation method is
constructed to study the model. The constructed model was became dimensionless from
for reducing stiffness to conduct the computational experiment. The computational experiment was implemented taking into account the actual technological conditions of
catalyst oxidative regeneration. The pictures of the distribution of concentrations and
mass fractions of coke in the pores of the catalyst grain are presented in conclusion.
Keywords:
oxidative regeneration, nonlinear model, chemical kinetics, stiff system, integro-interpolation method.
Received: 24.01.2022 Revised: 06.07.2022 Accepted: 12.09.2022
Citation:
I. M. Gubaydullin, E. E. Peskova, O. S. Yazovtseva, A. N. Zagoruiko, “Numerical simulation of oxidative regeneration of a spherical catalyst grain”, Matem. Mod., 34:11 (2022), 48–66
Linking options:
https://www.mathnet.ru/eng/mm4418 https://www.mathnet.ru/eng/mm/v34/i11/p48
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Abstract page: | 235 | Full-text PDF : | 36 | References: | 47 | First page: | 15 |
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