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Mendeleev Communications, 2021, Volume 31, Issue 1, Pages 20–23
DOI: https://doi.org/10.1016/j.mencom.2021.01.005
(Mi mendc821)
 

This article is cited in 9 scientific papers (total in 9 papers)

Communications

Polyaromatic-terminated iron(ii) clathrochelates as electrocatalysts for efficient hydrogen production in water electrolysis cells with polymer electrolyte membrane

A. S. Pushkareva, I. V. Pushkarevaa, M. A. Solovyevab, S. A. Grigorievabcd, Ya. Z. Voloshincef, N. V. Chornenkag, A. S. Belovc, P. Milleth, M. Antuchh, V. N. Kalinichenkoi, A. G. Dedovef

a National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
b National Research University ‘Moscow Power Engineering Institute,’ Moscow, Russian Federation
c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
d HySA Infrastructure Center of Competence, Faculty of Engineering, North-West University, Potchefstroom, South Africa
e National University of Oil and Gas ‘Gubkin University’, Moscow, Russian Federation
f N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
g V.I. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
h Institut de Chimie Moléculaire et des Matériaux d’Orsay, Université Paris-Saclay, Orsay, France
i N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (314 kB) Citations (9)
Abstract: Hydrogen-evolving cathodes were prepared using a series of iron(ii) clathrochelates bearing various number of terminal phenanthrenyl groups via physisorption on carbon paper and employed in the polymer electrolyte membrane water electrolysis cells instead of typically used platinum. In situ electrochemical activation of the cathodes was carried out, after that the cells performance and durability were evaluated. These clathrochelate complexes represent a promising alternative to platinum as hydrogen-evolving cathode electrocatalysts.
Keywords: macrocyclic compounds, clathrochelates, hydrogen evolution reaction, polymer electrolyte membrane, water electrolysis, electrocatalyst.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (461.3 Kb)


Citation: A. S. Pushkarev, I. V. Pushkareva, M. A. Solovyev, S. A. Grigoriev, Ya. Z. Voloshin, N. V. Chornenka, A. S. Belov, P. Millet, M. Antuch, V. N. Kalinichenko, A. G. Dedov, “Polyaromatic-terminated iron(ii) clathrochelates as electrocatalysts for efficient hydrogen production in water electrolysis cells with polymer electrolyte membrane”, Mendeleev Commun., 31:1 (2021), 20–23
Linking options:
  • https://www.mathnet.ru/eng/mendc821
  • https://www.mathnet.ru/eng/mendc/v31/i1/p20
  • This publication is cited in the following 9 articles:
    1. E. A. Chistyakova, M. O. Orlov, D. A. Moiseenkova, N. A. Nazarov, A. K. Osipov, “Problems and Prospects of Production of “Green” Hydrogen (a Review)”, Theor Found Chem Eng, 58:2 (2024), 370  crossref
    2. S. I. Butrim, M. A. Solovyev, I. V. Pushkareva, V. V. Tishkin, D. A. Simkin, B. L. Shapir, M. V. Kozlova, O. K. Alekseeva, E. V. Kukueva, A. S. Pushkarev, V. N. Fateev, “The Research and Development of the Titanium Nitrides TiNx Sublayer, Formed on the Surface of the Anodic Porous Transport Layer of PEM Water Electrolyzer”, Nanotechnol Russia, 18:S2 (2023), S367  crossref
    3. M. V. Kozlova, I. V. Pushkareva, S. I. Butrim, M. A. Solovyev, D. A. Simkin, S. A. Grigoriev, A. S. Pushkarev, “Investigation of the Degradation of the Membrane Electrode Assembly for a Proton Exchange Membrane Water Electrolyzer by Accelerated Stress Tests”, Nanotechnol Russia, 18:S2 (2023), S375  crossref
    4. Marco Bellini, Jonas Bösken, Michael Wörle, Debora Thöny, Juan José Gamboa-Carballo, Frank Krumeich, Francesco Bàrtoli, Hamish A. Miller, Lorenzo Poggini, Werner Oberhauser, Alessandro Lavacchi, Hansjörg Grützmacher, Francesco Vizza, “Remarkable stability of a molecular ruthenium complex in PEM water electrolysis”, Chem. Sci., 13:13 (2022), 3748  crossref
    5. A. S. Pushkarev, I. V. Pushkareva, M. V. Kozlova, M. A. Solovyev, S. I. Butrim, J. Ge, W. Xing, V. N. Fateev, “Heteroatom-Modified Carbon Materials and Their Use as Supports and Electrocatalysts in Proton Exchange Membrane Fuel Cells (A Review)”, Russ J Electrochem, 58:7 (2022), 529  crossref
    6. Suchetha Shetty, Noorullah Baig, Saleh Al‐Mousawi, Bassam Alameddine, “Removal of anionic and cationic dyes using porous copolymer networks made from a Sonogashira cross‐coupling reaction of diethynyl iron (II) clathrochelate with various arylamines”, J of Applied Polymer Sci, 139:43 (2022)  crossref
    7. Dan Tang, Yanfang Ma, Yang Liu, Keke Wang, Zeng Liu, Wenzhang Li, Jie Li, “Amorphous three-dimensional porous Co3O4 nanowire network toward superior OER catalysis by lithium-induced”, Journal of Alloys and Compounds, 893 (2022), 162287  crossref
    8. A.S. Pushkarev, I.V. Pushkareva, M.A. Solovyev, M. Prokop, T. Bystron, S.K. Rajagopalan, K. Bouzek, S.A. Grigoriev, “On the influence of porous transport layers parameters on the performances of polymer electrolyte membrane water electrolysis cells”, Electrochimica Acta, 399 (2021), 139436  crossref
    9. Pouya Barnoon, “Modeling of a high temperature heat exchanger to supply hydrogen required by fuel cells through reforming process”, Energy Reports, 7 (2021), 5685  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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