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Mendeleev Communications, 2024, Volume 34, Issue 2, Pages 192–194
DOI: https://doi.org/10.1016/j.mencom.2024.02.010
(Mi mendc79)
 

Communications

Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)]

D. V. Sedlovaab, E. S. Osipovaa, E. I. Gutsula, I. A. Godovikova, O. A. Filippova, E. S. Shubinaa, N. V. Belkovaa

a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Moscow Institute of Physics and Technology (National Research University), Dolgoprudny, Moscow Region, Russian Federation
Abstract: The interaction of bimetallic (t-BuPCP)Pd···(OC)M(CO)2 Cp (M = Mo, W) complexes with PhSiH3 leads to an efficient heterolytic splitting of Si–H bond that is a primary step in catalytic hydrosilylation of CO2. The reaction can be stopped at the formate level in the presence of the above complexes while proceeds further when catalyzed by (t-BuPCP)PdH.
Keywords: bimetallic catalysis, pincer complexes, carbon dioxide, hydrosilylation, reaction mechanism, IR spectroscopy.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.8 Mb)


Citation: D. V. Sedlova, E. S. Osipova, E. I. Gutsul, I. A. Godovikov, O. A. Filippov, E. S. Shubina, N. V. Belkova, “Stepwise carbon dioxide hydrosilylation catalyzed by bimetallic complexes [CpM(CO)2(μ-CO)···Pd(t-BuPCP)]”, Mendeleev Commun., 34:2 (2024), 192–194
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