R. Fischer, Ch. Marschner, “Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides”, Mendeleev Commun., 32:1 (2022), 52

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Mendeleev Communications, 2022, Volume 32, Issue 1, Pages 52–53
DOI: https://doi.org/10.1016/j.mencom.2022.01.016 (Mi mendc568)

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides

R. Fischer, Ch. Marschner

Institute für Anorganische Chemie, Technische Universität Graz, Graz, Austria

Full-text PDF (406 kB) Citations (2)

DOI: https://doi.org/10.1016/j.mencom.2022.01.016

Graphic abstract: Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides

Abstract: Reactions of (Me₃Si)₃SnK with Cp₂MCl₂ (M = Zr, Hf) give the respective stannylated metallocene chlorides. These complexes display a tendency to eliminate bis(trimethylsilyl)-stannylene under Cp₂M(Cl)SiMe₃ formation.

Keywords: Stannylated compounds, Group 4 elements, Metallocenes, Stannylene, Tin, Silicon, Zirconium, Hafnium.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.2 Mb)

Citation: R. Fischer, Ch. Marschner, “Elimination of bis(trimethylsilyl)stannylene from tris(trimethylsilyl)stannylated zirconocene and hafnocene chlorides”, Mendeleev Commun., 32:1 (2022), 52–53

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https://www.mathnet.ru/eng/mendc568

https://www.mathnet.ru/eng/mendc/v32/i1/p52

This publication is cited in the following 2 articles:

K. I. Tugashov, M. V. Andreev, M. A. Frolov, V. S. Bogdanov, A. F. Smol'yakov, F. M. Dolgushin, V. V. Burlakov, “Synthesis and structure of the first bromide complex of the four-mercury anticrown [(o,o'-C6F4C6F4Hg)4Br]-”, Mendeleev Commun., 34:2 (2024), 188–191
M. V. Andreev, V. S. Bogdanov, M. A. Frolov, E. R. Nurzhanova, A. F. Smol'yakov, V. V. Burlakov, “Protolysis of five-membered metallacyclocumulene complexes of zirconocene and hafnocene”, Mendeleev Commun., 33:6 (2023), 750–752

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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