Abstract:
The first examples of germanium and tin complexes with α-diimine ligands undergoing reversible redox isomeric (valence tautomeric) rearrangements were demonstrated based on the computational modeling of their dynamic behavior using DFT at the B3LYP/Def2TZVP level.
Keywords:
Group 14 elements, Diimines, Bis-chelates, Valence tautomerism, DFT calculations.
Citation:
M. G. Chegerev, A. A. Starikova, A. G. Starikov, V. I. Minkin, “Computational search for redox isomerism in Ge and Sn bis-chelates with α-diimine ligands”, Mendeleev Commun., 32:1 (2022), 49–51
Linking options:
https://www.mathnet.ru/eng/mendc567
https://www.mathnet.ru/eng/mendc/v32/i1/p49
This publication is cited in the following 2 articles:
E. P. Ivakhnenko, Yu. G. Vitkovskaya, K. A. Lysenko, S. E. Kislitsyn, A. G. Starikov, P. A. Knyazev, A. A. Tereshchenko, V. I. Minkin, “Zinc(II) Chelate Complexes with Redox-Active o-Indophenols: Synthesis and Structure”, Russ. J. Inorg. Chem., 68:9 (2023), 1159
E. P. Ivakhnenko, Yu. G. Vitkovskaya, K. A. Lysenko, S. E. Kislitsyn, A. G. Starikov, P. A. Knyazev, A. A. Tereshchenko, V. I. Minkin, “Zinc(II) Chelate Complexes with Redox-Active o-Indophenols: Synthesis and Structure”, Žurnal neorganičeskoj himii, 68:9 (2023), 1181
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