Abstract:
Experimental evidence for the isoparametricity phenomenon has been obtained: at critical values of σˆx constants of substituents X in anilines, the rate of nucleophilic displacement does not change with variation in substituents Y in benzoyl halides and benzyl bromides; after passing through the critical values of σˆx the order of reactivity for both substrates is reversed.
Document Type:
Article
Language: English
Citation:
I. V. Shpan'ko, “The Isoparametricity Phenomenon in the Reactions of Benzoyl Halides and Benzyl Bromides with Anilines”, Mendeleev Commun., 1:4 (1991), 119–120
Linking options:
https://www.mathnet.ru/eng/mendc5534
https://www.mathnet.ru/eng/mendc/v1/i4/p119
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