Abstract:
It has been shown that the C–F bond may be selectively hydrogenolysed under the action of HSiEt3 in the presence of AICI3, when the α-position of the C–F bond is occupied by a phenyl group or by a heteroatom with an unshared electron pair
Document Type:
Article
Language: English
Citation:
M. E. Vol'pin, N. V. Shevchenko, G. I. Bolestova, I. G. Abramov, Yu. A. Fialkov, Z. N. Parnes, “Selective Hydrogenolysis of the C–F Bond”, Mendeleev Commun., 1:4 (1991), 118–119
Linking options:
https://www.mathnet.ru/eng/mendc5533
https://www.mathnet.ru/eng/mendc/v1/i4/p118
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Timo Stahl, Hendrik F. T. Klare, Martin Oestreich, “Main-Group Lewis Acids for C–F Bond Activation”, ACS Catal., 3:7 (2013), 1578
Timo Stahl, Hendrik F. T. Klare, Martin Oestreich, “C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle”, J. Am. Chem. Soc., 135:4 (2013), 1248
Moritz F. Kuehnel, Philipp Holstein, Meike Kliche, Juliane Krüger, Stefan Matthies, Dominik Nitsch, Joseph Schutt, Michael Sparenberg, Dieter Lentz, “Titanium‐Catalyzed Vinylic and Allylic CF Bond Activation—Scope, Limitations and Mechanistic Insight”, Chemistry A European J, 18:34 (2012), 10701
M. E. VOL'PIN, N. V. SHEVCHENKO, G. I. BOLESTOVA, YU. V. ZEIFMAN, YU. A. FIALKOV, Z. N. PARNES, “ChemInform Abstract: Selective Hydrogenolysis of the C‐F Bond.”, ChemInform, 23:24 (1992)
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