Abstract:
UV photolysis of luminol (5-amino-2,3-dihydrophthalazine-1,4-dione) in aqueous solution via one-photon photoionization gives the luminol radical and an hydrated electron, which reacts with the dissolved oxygen to form the superoxide radical; recombination of the luminol radical with superoxide leads to chemiluminescence
Document Type:
Article
Language: English
Citation:
S. F. Lebedkin, A. D. Klimov, V. N. Emokhonov, “Photoionization and Photochemiluminescence of Luminol in Aqueous Solution”, Mendeleev Commun., 3:5 (1993), 203–204
Linking options:
https://www.mathnet.ru/eng/mendc5334
https://www.mathnet.ru/eng/mendc/v3/i5/p203
This publication is cited in the following 2 articles:
Qichao Chen, Cai Ning, Jiawen Fang, Boyu Ping, Guiyang Li, Lingqiao Kong, Jiayi Chen, ZhengMing Sun, Jinlan Wang, Qiushi Ruan, Xianghong Niu, Li Tao, “Redirecting the electron flow to coordinate oxidation and reduction reactions for efficient photocatalytic H2O2 production”, Chemical Engineering Journal, 487 (2024), 150581
Lingyue Min, Xing‐Zheng Wu, “Chemiluminescence from luminol solution after illumination of a 355 nm pulse laser”, Luminescence, 24:6 (2009), 400
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