Abstract:
Treatment of iron complex (η5-C5H5)Fe(CO)2CH2C≡CPh 1 with nitrogen-containing 1,3-dipolar reagents (nitrile oxides and azomethine ylide) yields six-membered σ-heterocyclic iron complexes, due to cycloaddition and subsequent 1,2-migration of the (η5–C5H5)2Fe (CO) group.
Document Type:
Article
Language: English
Citation:
V. N. Kalinin, M. A. Yakovleva, V. V. Derunov, “Synthesis of σ-Heterocyclic Iron Complexes Based on [3+3] Cycloaddition to 1,3-Dipolar Reagents”, Mendeleev Commun., 3:5 (1993), 202–203
Linking options:
https://www.mathnet.ru/eng/mendc5333
https://www.mathnet.ru/eng/mendc/v3/i5/p202
This publication is cited in the following 2 articles:
Nadezhda A. Bokach, Anatolii V. Khripoun, Vadim Yu. Kukushkin, Matti Haukka, Armando J. L. Pombeiro, “A Route to 1,2,4-Oxadiazoles and Their Complexes via Platinum-Mediated 1,3-Dipolar Cycloaddition of Nitrile Oxides to Organonitriles”, Inorg. Chem., 42:3 (2003), 896
V. N. KALININ, M. A. YAKOVLEVA, V. V. DERUNOV, “ChemInform Abstract: Synthesis of σ‐Heterocyclic Iron Complexes Based on (3 + 3) Cycloaddition to 1,3‐Dipolar Reagents.”, ChemInform, 25:15 (1994)
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