Abstract:
Bands resulting from contact outer-sphere anion-anion interactions, have been found in the electronic absorption spectra of systems containing simultaneously the anions [FeNO(CN)5]2– or [Co edta]– and nucleophilic anions (I−,SCN−andS2O32−); the fraction of complex anions occurring in the contact interaction with nucleophilic anions can be as high as several tens of percent in concentrated solutions.
Document Type:
Article
Language: English
Citation:
A. B. Nikol'skii, V. Yu. Kotov, “Outer-sphere Anion-Anion Complexes”, Mendeleev Commun., 5:4 (1995), 139–140
Linking options:
https://www.mathnet.ru/eng/mendc5069
https://www.mathnet.ru/eng/mendc/v5/i4/p139
This publication is cited in the following 8 articles:
Dimitri E. Khoshtariya, Tinatin D. Dolidze, Lasha Laliashvili, Nikoloz Nioradze, “Forty years of theory-inspired experiments on charge-transfer via solutions and electrodes: the Georgian accents”, J Solid State Electrochem, 27:7 (2023), 1593
A. A. Krotova, V. Yu. Kotov, “Unusual stability of anionic associates in mixed solvents”, Mendeleev Commun., 26:2 (2016), 154–156
Yulia V. Nelyubina, Konstantin A. Lyssenko, Vitalii Yu. Kotov, Mikhail Yu. Antipin, “Anion-Anion Assembly in Crystal of Sodium Nitroprusside”, J. Phys. Chem. A, 112:37 (2008), 8790
V. Yu. Kotov, Yu. G. Gorbunova, S. A. Kostina, G. K. Kadorkina, V. R. Kostyanovsky, R. G. Kostyanovsky, “Outer-sphere association of hexacyanoferrate and nitrogen betaine anions”, Mendeleev Commun., 11:5 (2001), 181–182
V. Yu. Kotov, “Calculation of activation-controlled reaction rate constants from parameters of electronic absorption spectra of ion pairs”, Russ Chem Bull, 49:6 (2000), 1002
S. I. Gorel'skii, T. G. Kim, T. P. Klimova, V. Yu. Kotov, B. V. Lokshin, Yu. D. Perfil'ev, T. I. Sherbak, G. A. Tsirlina, “Outer-sphere anion–anion charge transfer in a solid hexacyanoferrate”, Mendeleev Commun., 10:3 (2000), 86–88
V. Yu. Kotov, S. I. Gorel'sky, “Outer-sphere interactions between anions”, Russ Chem Bull, 48:5 (1999), 823
V. Yu. Kotov, G. A. Tsirlina, “Close contact distance between hexacyanometallate ions in the course of electron transfer”, Mendeleev Commun., 9:5 (1999), 181–182
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