Abstract:
Quantum rate constant evaluations and kinetic isotope effects for the oxidative addition of CH4 (and CD4) to a bare Pd atom, calculated in terms of the Reaction Path Hamiltonian approximation, show quantum tunneling to play a very important role in the process when T < 200 K.
Document Type:
Article
Language: English
Citation:
V. M. Mamaev, I. P. Gloriozov, S. Ya. Ishchenko, V. V. Simonyan, E. M. Myshakin, A. V. Prisyajnuk, Yu. A. Ustynyuk, “Tunneling in the Oxidative Addition Reaction of Methane to a Bare Palladium Atom”, Mendeleev Commun., 5:4 (1995), 137–138
Linking options:
https://www.mathnet.ru/eng/mendc5068
https://www.mathnet.ru/eng/mendc/v5/i4/p137
This publication is cited in the following 1 articles:
Catalysis by Metal Complexes, 21, Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, 2002, 219
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