Abstract:
Unusually easy dequaternization has been found to occur on treatment of 1-alkyl-3-morpholino-5-phenyl-1,2,4-triazinium iodides with triethylamine in alcohol or acetone solutions at room temperature; a plausible reaction mechanism has been advanced on the basis of NMR and kinetic studies.
Document Type:
Article
Language: English
Citation:
O. N. Chupakhin, B. V. Rudakov, P. McDermott, S. G. Alexeev, V. N. Charushin, F. Hegarty, “An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts”, Mendeleev Commun., 5:3 (1995), 104–105
Linking options:
https://www.mathnet.ru/eng/mendc5052
https://www.mathnet.ru/eng/mendc/v5/i3/p104
This publication is cited in the following 5 articles:
Juraj Galeta, Veronika Šlachtová, Martin Dračínský, Milan Vrabel, “Regio- and Diastereoselective 1,3-Dipolar Cycloadditions of 1,2,4-Triazin-1-ium Ylides: a Straightforward Synthetic Route to Polysubstituted Pyrrolo[2,1-f][1,2,4]triazines”, ACS Omega, 7:24 (2022), 21233
Irina D. Yushina, Boris V. Rudakov, Adam I. Stash, Ekaterina V. Bartashevich, “Comparison of non-covalent interactions and spectral properties in 1-methyl-3-methylthio-5-phenyl-1,2,4-triazinium mono- and tetraiodide crystals”, Struct Chem, 30:5 (2019), 1981
V. Charushin, V. Rusinov, O. Chupakhin, Comprehensive Heterocyclic Chemistry III, 2008, 95
Derek T. Hurst, Progress in Heterocyclic Chemistry, 9, 1997, 268
Derek T. Hurst, Progress in Heterocyclic Chemistry, 8, 1996, 255